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Enhancement of Nonlinear Optical Properties Through Supramolecular Chirality

Published online by Cambridge University Press:  10 February 2011

S. Van Elshocht ,
B. Busson ,
T. Verbiest ,
M. Kauranen ,
J. Snauwaert ,
L. Hellemans ,
A. Persoons ,
C. Nuckolls  and
T.J. Katz
S. Van Elshocht
Affiliation:
Laboratory of Chemical and Biological Dynamics, University of Leuven, Celestijnenlaan 200D, B-3001 Heverlee, Belgium
B. Busson
Affiliation:
Laboratory of Chemical and Biological Dynamics, University of Leuven, Celestijnenlaan 200D, B-3001 Heverlee, Belgium
T. Verbiest
Affiliation:
Laboratory of Chemical and Biological Dynamics, University of Leuven, Celestijnenlaan 200D, B-3001 Heverlee, Belgium
M. Kauranen
Affiliation:
Laboratory of Chemical and Biological Dynamics, University of Leuven, Celestijnenlaan 200D, B-3001 Heverlee, Belgium
J. Snauwaert
Affiliation:
Laboratory of Chemical and Biological Dynamics, University of Leuven, Celestijnenlaan 200D, B-3001 Heverlee, Belgium
L. Hellemans
Affiliation:
Laboratory of Chemical and Biological Dynamics, University of Leuven, Celestijnenlaan 200D, B-3001 Heverlee, Belgium
A. Persoons
Affiliation:
Laboratory of Chemical and Biological Dynamics, University of Leuven, Celestijnenlaan 200D, B-3001 Heverlee, Belgium
C. Nuckolls
Affiliation:
Department of Chemistry, Columbia University, New York, NY 10027, USA
T.J. Katz
Affiliation:
Department of Chemistry, Columbia University, New York, NY 10027, USA
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Abstract

We study second-order nonlinear optical properties of enantiomerically pure and racemic Langmuir-Blodgett films of a chiral helicenebisquinone. Supramolecular aggregation of the material enhances the nonlinear efficiency of the enantiomerically pure material. We also show that the material is potentially useful for constructing quasi-phase-matched structures for frequency conversion.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 561: Symposium F – Organic Nonlinear Optical Materials and Devices , 1999 , 15
Copyright
Copyright © Materials Research Society 1999

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References

REFERENCES

[1] Prasad, P.N. and Williams, D.J., Introduction to Nonlinear Optical Effects in Molecules and Polymers, Wiley, New York, 1991.Google Scholar
[2] Roberts, G., Langmuir-Blodgettfilms, Plenum, New York, 1990.Google Scholar
[3] Ulman, A., An introduction to ultrathin organicfllmsfrom Langmuir-Blodgett to selfassembly, Academic Press, San Diego, 1991.Google Scholar
[4] Miyato, S. and Sasabe, H., Advances in nonlinear optics vol.4 : Poled polymers and their applications to SHG and EO devices, Gordon and Breach Publishers, Singapore, 1997.Google Scholar
[5] Bossard, Ch., Sutter, K., Pretre, Ph., Hulliger, J., Flbrsheimer, M., Kaatz, P., and Giinter, P., Advances in nonlinear optics vol.1 : Organic nonlinear optical materials, Gordon and Breach Publishers, Singapore, 1995.Google Scholar
[6] Rentzepis, P.M., Giordmaine, J.A., Wecht, K.W., Phys. Rev. Lett. 16, 792 (1966).Google Scholar
[7] Zyss, J. and Chemla, D.S., Nonlinear optical properties of organic molecules and crystals, Chemla, D.S. and Zyss, J. Eds. Vol.1, Academic Press, Orlando, 1987.Google Scholar
[8] Nuckolls, C., Katz, T.J., Castellanos, L., J. Am. Chem. Soc. 118, 3767 (1996).Google Scholar
[9] Lovinger, A.J., Nuckolls, C., Katz, T.J., J. Am. Chem. Soc. 120, 264 (1998).Google Scholar
[10] Nuckolls, C., Katz, T.J., Katz, G., Collins, P.J., Castellanos, L., in preparation.Google Scholar
[11] Fejer, M.M., Magel, G.A., Jundt, D.H., Byer, R.L., IEEE J. Quantum Electron. 28, 2631 (1992).Google Scholar
[12] Kauranen, M., Maki, J.J., Verbiest, T., Elshocht, S. Van, Persoons, A., Phys. Rev. B 55, R1985 (1997).Google Scholar
[13] Maki, J.J., Kauranen, M., and Persoons, A., Phys. Rev. B 51, 1425 (1995).Google Scholar
[14] Zhuang, X., Wilk, D., Marrucci, L., Shen, Y.R., Phys, Rev. Lett. 75, 2144 (1995).Google Scholar
[15] Roberts, D., IEEE J. Quantum Electron. 28, 2057 (1992).Google Scholar
[16] Nassoy, P., Goldmann, M., Boulossa, O., Rondelez, F., Phys. Rev. Lett. 75, 457 (1995).Google Scholar
[17] Ref.: Kang, J. U., Ding, Y. J., Bums, W. K. and Melinger, J. S., Opt. Lett. 22, pp 862–864 (1997).Google Scholar