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Engineered Three-dimensional Colloidal Crystals Containing a Planar Defect

Published online by Cambridge University Press:  26 February 2011

Pascal Massé ,
Beatrice Agricole ,
Elisabeth Sellier  and
Serge Ravaine
Pascal Massé
Affiliation:
[email protected], Centre de Recherche Paul Pascal, 115 avenue du Dr Schweitzer, Pessac, N/A, 33600, France, 33 5 56 84 56 77, 33 5 56 84 56 00
Beatrice Agricole
Affiliation:
[email protected], Centre de Recherche Paul Pascal
Elisabeth Sellier
Affiliation:
[email protected], Centre de Ressources En Microscopie Electronique et Microanalyse
Serge Ravaine
Affiliation:
[email protected], Centre de Recherche Paul Pascal
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Abstract

We have fabricated three-dimensional (3D) colloidal crystals containing a two-dimensional (2D) defect as the middle layer by the Langmuir-Blodgett (LB) technique. Either a homogeneous sheet made of hundreds layers of behenic acid or a single monolayer of silica colloidal particles of various sizes was inserted between two opal films of silica spheres. The presence of the extrinsic defect led to an impurity mode within the photonic stop band, which was observed as a pass band in the near-infrared (NIR) spectra. The position of this defect mode was found to vary periodically with the value of the ratio of the thickness of the defect layer to the diameter of the colloids of the upper and lower opals.

Keywords

colloidcrystaldefects
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 901: Symposium R – Assembly at the Nanoscale – Toward Functional Nanostructured Materials , 2005 , 0901-Ra05-19-Rb05-19
Copyright
Copyright © Materials Research Society 2006

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