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Published online by Cambridge University Press: 25 February 2011
We report electron-radiation-induced epitaxial growth of CoSi2 on Si(111) from an amorphous Co/Si 1:2 mixture with epitaxial CoSi2 nuclei. Under the electron beam of a Philips EM430 electron microscope, the epitaxial nuclei grow parallel to the surface with a growth rate orders of magnitude higher than that for thermally activated growth. The substrate temperature during irradiation and the electron energy dependence were studied. Electron-radiation-induced growth shows very weak temperature dependence in the temperatures between 100°K and 300°K and the activation energy is 0.03 eV. The growth rate increases significantly as the electron energy increased to 200 KeV which is about the threshold energy for displacing Si atoms.