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Electronic and Magnetic Properties of d1 Pnictide-Oxides: Na2Ti2Pn2O (Pn = As, Sb)

Published online by Cambridge University Press:  18 March 2011

Tadashi C. Ozawa ,
Mario Bieringer ,
John E. Greedan  and
Susan. M. Kauzlarich
Tadashi C. Ozawa
Affiliation:
University of California One Shields Avenue Davis, CA 95616, U.S.A
Mario Bieringer
Affiliation:
Institute for Materials Research McMaster University Hamilton, Ontario L8S 4M1, Canada
John E. Greedan
Affiliation:
Institute for Materials Research McMaster University Hamilton, Ontario L8S 4M1, Canada
Susan. M. Kauzlarich
Affiliation:
University of California One Shields Avenue Davis, CA 95616, U.S.A
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Abstract

Bulk physical properties of layered pnictide-oxides, Na2Ti2Pn2O (Pn = As, Sb) have been characterized. Both As and Sb compounds exhibit anomalous transitions in temperature dependent magnetic susceptibility and electrical resistivity. The powder neutron diffraction data show no superlattice reflections indicative of long-range order. The origin of the physical property anomalies and structure-property relationship between As and Sb compounds are described in terms of a charge-density-wave/spin-density-wave mechanism.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 658: Symposium GG – Solid-State Chemistry of Inorganic Materials III , 2000 , GG4.1
Copyright
Copyright © Materials Research Society 2001

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References

REFERENCES

1. Adam, A. and Schuster, H.-U., Z. Anorg. Allg. Chem., 584, 150 (1990).Google Scholar
2. Axtell, E. A. III, Ozawa, T., Kauzlarich, S. M. and Singh, R. R. P., J. Solid State Chem., 134, 423 (1997).Google Scholar
3. Ozawa, T. C., Pantoja, R., Axtell, E. A. III, Kauzlarich, S. M., Greedan, J. E., Bieringer, M. and Richardson, J. W. Jr, J. Solid State Chem., 153, 275 (2000).Google Scholar
4. Ramanujachary, K. V., Collins, B. T. and Greenblatt, M., Solid State Comm., 59, 647 (1986).Google Scholar
5. Greenblatt, M., Acc. Chem. Res., 29, 219 (1996).Google Scholar
6. Kagoshima, S., Nagasawa, H. and Sambongi, T., One-Dimensional Conductors, (Springer-Verlag, 1988) p.102.Google Scholar
7. Dumas, J., Schlenker, C., Markus, J. and Buder, R., Phys. Rev. Lett., 50, 757 (1983).Google Scholar
8. Kagoshima, S., Nagasawa, H. and Sambongi, T., One-Dimensional Conductors, (Springer-Verlag, 1988) p.205.Google Scholar
9. Pickett, W. E., Phys. Rev. B., 58, 4335 (1998).Google Scholar
10. Biani, F. Fabrizi de, Alemany, P. and Canadell, E., Inorg. Chem., 37, 5807 (1998).Google Scholar