Hostname: page-component-cd9895bd7-dk4vv Total loading time: 0 Render date: 2024-12-27T01:14:58.904Z Has data issue: false hasContentIssue false
  • English
  • Français

Electrodeposition of 3-D Size-Quantized Cds and CdSe Films

Published online by Cambridge University Press:  21 February 2011

G. Hodes ,
T. Engelhard ,
A. Albu-Yaron  and
A. Pettford-Long
G. Hodes
Affiliation:
Dept. of Materials Research, Weizmann Institute of Science, Rehovot, 76100, Israel
T. Engelhard
Affiliation:
Dept. of Materials Research, Weizmann Institute of Science, Rehovot, 76100, Israel
A. Albu-Yaron
Affiliation:
ARO, The Volcani Center, P.O.B. 4, Bet-Dagan 50-250, Israel
A. Pettford-Long
Affiliation:
Dept. of Metallurgy and Science of Materials, University of Oxford, OX1 3PH, UK
Get access

Abstract

CdS and CdSe films electrodeposited from chalcogen-containing non-aqueous electrolytes are shown to possess a nanocrystalline structure and exhibit 3-D quantum size effects. A large variation in optical transmission spectra, due for the most part to this sizequantization, is shown. Photoelectrochemical activity of the as-deposited films is discussed in terms of their nano-structure. Extension of the crystallite size effects to a metalinsulator transition in MoO2 deposited from a similar electrolyte is mentioned.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 164: Symposium H – Materials Issues in Microcrystalline Semiconductors , 1989 , 81
Copyright
Copyright © Materials Research Society 1990

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1) Baranski, A.S. and Fawcett, W.R., J. Electrochem. Soc., 127, 766 (1980).Google Scholar
2) Baranski, A.S., Fawcett, W.R., McDonald, A.C., Nobriga, R.M. de and MacDonald, J.R., J. Electrochem. Soc., 12A, 963 (1981).Google Scholar
3) Baranski, A.S., Bennett, M.S. and Fawcett, W.R., J. Appl. Phys., 54, 6390 (1983).Google Scholar
4) Baranski, A.S., Fawcett, W.R., Gatner, K., McDonald, A.C., MacDonald, J.R. and Selen, M., J. Electrochem. Soc., 130, 579 (1983).Google Scholar
5) Fatas, E., Herrasti, P., Garcia, T., Arjona, F. and Camarero, E. Garcia, Maters. Chem. and Phys. 13, 497 (1985).Google Scholar
6) Preusser, S. and Cocivera, M., Solar Energy Mats, 15, 175 (1987).Google Scholar
7) Sanders, B.W. and Cocivera, M., J. Electrochem. Soc., 134, 1075 (1987).Google Scholar
8) Mishra, K., Rajeshwar, K., Weiss, A., Murley, M., Engelken, R.D., Slayton, M. and McCloud, H.E., J. Electrochem. Soc., 136, 1915 (1989).Google Scholar
9) Hodes, G., Albu-Yaron, A., Decker, F. and Motisuke, P., Phys. Rev. B., 36, 421 (1987).Google Scholar
10) Hodes, G. and Albu-Yaron, A., Proc. Electrochem. Soc., 88–14, 298 (1988).Google Scholar
11) Baranski, A.S. and Fawcett, W.R., J. Electrochem. Soc., 131, 2509 (1984).Google Scholar