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Electrochemical Polymerization of Conducting Polymer Coatings on Neural Prosthetic Devices: Nanomushrooms of Polypyrrole Using Block Copolymer Thin Films as Templates

Published online by Cambridge University Press:  11 February 2011

Junyan Yang
Affiliation:
Department of Materials Science and Engineering, University of Michigan, Ann Arbor, MI 48109
Yinghong Xiao
Affiliation:
Department of Materials Science and Engineering, University of Michigan, Ann Arbor, MI 48109
David C. Martin
Affiliation:
Department of Materials Science and Engineering, University of Michigan, Ann Arbor, MI 48109 Macromolecular Science and Engineering Center, University of Michigan, Ann Arbor, MI 48109 Department of Biomedical Engineering, University of Michigan, Ann Arbor, MI 48109
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Abstract

We have demonstrated a method to rapidly and reliably fabricate arrays based on the self-assembled morphology of block copolymer ultra thin films. An ordered, nanoporous structure obtained from the block copolymer thin films is used a template for the subsequent electrodeposition of conducting polymer nanomushrooms of polypyrrole (PPy). The influence of current density, deposition charge and morphology of the templates and nanostructured conducting polymer coatings has been investigated. The electrical properties of the polymer coatings were studied.

Type
Research Article
Copyright
Copyright © Materials Research Society 2003

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References

REFERENCES

1. Cui, X., Hetke, J. F., Wiler, J. A., Anderson, D. J. and Martin, D. C., Sensors and Actuators A: Physical, 93(1): 8, (2001).CrossRefGoogle Scholar
2. Cui, X., Lee, V. A., Raphael, Y., Wiler, J. A., Hetke, J. F., Anderson, D. J. and Martin, D. C., Journal of Biomedical Materials Research, 56(2): 261, (2001).3.0.CO;2-I>CrossRefGoogle Scholar
3. Cui, X. and Martin, D. C., Sensors and Actuators B: Chemical (2002), in press.Google Scholar
4. Xiao, Y-H., Cui, X.. and Martin, D. C., MRS Meeting, Dec. Boston, MAGoogle Scholar
5. Suri, K., Annapoorni, S., Sakar, A. K. and Tandon, R. P., Sensor and Actuators B: 81, 277 (2002)CrossRefGoogle Scholar
6. He, H., Zhu, J., Tao, J, Nagahara, L. A., Amlani, I, and Tsui, R., J. Am. Chem. Soc., 123, 7730 (2001)CrossRefGoogle Scholar
7. Wallace, G. G. and Innis, P. C., Nanoscience and Nanotechnique, Vol. 2, No 5, 441 (2002)Google Scholar
8. Martin, C. R., Science, 266, 1961 (1994)CrossRefGoogle Scholar
9. Liang, W., and Martin, C.R., J. Am. Chem. Soc., 112, 8976 (1990)Google Scholar
10. Cai, Z., Lei, J., Liang, W., Menon, V., and Martin, C.R., Chem. Mater., 3, 960 (1990)CrossRefGoogle Scholar
11. Cai, Z., and Martin, C.R., J. Am. Chem. Soc., 111, 4139 (1989)CrossRefGoogle Scholar
12. Martin, C. R., Adv. Mater, 3, 457 (1991)CrossRefGoogle Scholar
13. Mansouri, J., and Burford, R. P., J. Membrane Sci., 87, 23(1994)CrossRefGoogle Scholar
14. Demoustier-Champagene, S., and Stavaux, P., Chem. Mater., 11, 829(1999)CrossRefGoogle Scholar
15. Mativetsky, J. M., and Datars, W. R., Solid State Communication, 122, 151 (2002)CrossRefGoogle Scholar
16. Ermolaev, S. V., Jitariouk, N., and Moel, A. L., Nuclear Instruments and Methods in Physics research B, 185, 184 (2001)CrossRefGoogle Scholar
17. Yang, J. and Martin, D. C., American Physical Society Meeting, March, Austin, TX 2003 (accepted)Google Scholar
18. Goren, M. and Lennox, R. B., Nanoletters, Vol. 1, NO. 12, 735 (2001)CrossRefGoogle Scholar
19. Park, M., Chaikin, P.M., Register, R. A. and Adamson, D. H., Applied Physics Letters, 79, 257 (2001)CrossRefGoogle Scholar
20. Thurn-Albrecht, T., Schotter, J., Kastle, G. A., Shibauchi, N Emley T., Krusin-Elbaum, L., Guarini, K., Black, C. T., Tuominen, M. T., and Russell, T. P., Science, 290, 2126 (2000)CrossRefGoogle Scholar
21. Mansky, P., Liu, Y., Russell, T. P., Huang, E., and Hawker, C., Science, 275, 1458(1997)CrossRefGoogle Scholar
22. Huang, E., Rockford, L., Russell, T. P., and Hawker, C. J., Nature, 395, 759(1998)CrossRefGoogle Scholar
23. Xu, T., Kim, H. C., Derouchey, J., Seney, C., Levesque, C., Martin, P., Stafford, C. M., and Russell, T. P., Polymer, 42, 9091(2001)CrossRefGoogle Scholar
24. Drummy, L. F., Yang, J. and Martin, D. C., 15th International Congress on Electron Microscopy, Durban, South Africa, 583584, September, 2002 Google Scholar