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Electrochemical catalytic behavior for platinum functionalized TiO2 nanotube arrays in PEM fuel cells

Published online by Cambridge University Press:  28 March 2013

Anurag Y Kawde ,
Alexander W O'Toole ,
Xiaoli He ,
Richard Phillips ,
Adam Lemke ,
Thomas Murray ,
Robert Geer  and
Eric Eisenbraun
Anurag Y Kawde
Affiliation:
College of Nanoscale Science and Engineering, State University of New York, Albany, NY 12222.
Alexander W O'Toole
Affiliation:
College of Nanoscale Science and Engineering, State University of New York, Albany, NY 12222.
Xiaoli He
Affiliation:
College of Nanoscale Science and Engineering, State University of New York, Albany, NY 12222.
Richard Phillips
Affiliation:
College of Nanoscale Science and Engineering, State University of New York, Albany, NY 12222.
Adam Lemke
Affiliation:
College of Nanoscale Science and Engineering, State University of New York, Albany, NY 12222.
Thomas Murray
Affiliation:
College of Nanoscale Science and Engineering, State University of New York, Albany, NY 12222.
Robert Geer
Affiliation:
College of Nanoscale Science and Engineering, State University of New York, Albany, NY 12222.
Eric Eisenbraun*
Affiliation:
College of Nanoscale Science and Engineering, State University of New York, Albany, NY 12222.
*
*Email: [email protected]
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Abstract

Conventional carbon electrode supports for platinum used in proton exchange membrane (PEM) fuel cell assemblies have issues related to carbon corrosion at typical cell operating and transient conditions. This corrosion gives rise to the evolution of greenhouse gases such as CO2, eventually degrading the carbon support and causing a loss of the catalyst specific area necessary to achieve the desired electrochemical performance. In this study, preliminary results are presented for Pt-functionalized TiO2 nanotube arrays as cathode catalyst supports for PEM fuel cells. The electrochemically synthesized TiO2 nanotube arrays were functionalized by different weight % of Pt via a solution-based approach using a dilute aqueous salt solution of hexachloroplatanic acid. Electron-beam based characterization techniques were used to study the structural and morphological features of the as-synthesized TiO2 nanotube arrays and functionalized Pt/TiO2 nanotube arrays. The electrochemical performance of the functionalized TiO2 nanotube arrays was studied by using cyclic voltammetry.

Keywords

electrochemical synthesisenergy storagenanostructure
Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1497: Symposium K – Hierarchically Structured Materials for Energy Conversion and Storage , 2013 , mrsf12-1497-k06-42
Copyright
Copyright © Materials Research Society 2013

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References

REFERENCES

Kawde, A., Vats, A., Shende, R., Puszynski, J., Nanotech Proceedings (2011) Vol. 1 747–750.Google Scholar
Winter, M., Brodd, R.J., ChemInform 35 (2004), 4245–4269.Google Scholar
Dusastre, V., Kilner, J., Solid State Ionics 126 (1999) 163–174.CrossRefGoogle Scholar
Huijsmans, J., Van Berkel, F., Christie, G., Journal of Power Sources 71 (1998) 107–110.CrossRefGoogle Scholar
Litster, S., McLean, G., Journal of Power Sources 130 (2004) 61–76.CrossRefGoogle Scholar
Lee, S., Mukerjee, S., McBreen, J., Rho, Y., Kho, Y., Lee, T., Electrochimica Acta 43 (1998) 3693–3701.CrossRefGoogle Scholar
Wilson, M.S., Gottesfeld, S., Journal of the Electrochemical Society 139 (1992) L28–L30.CrossRefGoogle Scholar
Seland, F., Berning, T., Børresen, B., Tunold, R., Journal of Power Sources 160 (2006) 27–36.CrossRefGoogle Scholar
Meyers, J.P., Darling, R.M., Journal of the Electrochemical Society 153 (2006) A1432–A1442.CrossRefGoogle Scholar
Qi, Z., Kaufman, A., Journal of Power Sources 113 (2003) 37–43.CrossRefGoogle Scholar
Tang, H., Qi, Z., Ramani, M., Elter, J.F., Journal of Power Sources 158 (2006) 1306–1312.CrossRefGoogle Scholar
Berning, T., Lu, D.M., Djilali, N., Journal of Power Sources 106 (2002) 284–294.CrossRefGoogle Scholar
Tian, M., Wu, G., Chen, A., ACS Catalysis 2 (2012) 425–432.CrossRefGoogle Scholar
Prakasam, H.E., Shankar, K., Paulose, M., Varghese, O.K., Grimes, C.A., The Journal of Physical Chemistry C 111 (2007) 7235–7241.CrossRefGoogle Scholar
Gong, D., Grimes, C., Varghese, O.K., Hu, W., Singh, R., Chen, Z., Dickey, E.C., Journal of Materials Research 16 (2001) 3331–3334.CrossRefGoogle Scholar
Mor, G., Varghese, O.K., Paulose, M., Mukherjee, N., Grimes, C., Journal of Materials Research 18 (2003) 2588–2593.CrossRefGoogle Scholar
Varghese, O.K., Gong, D., Paulose, M., Ong, K.G., Dickey, E.C., Grimes, C.A., Advanced Materials 15 (2003) 624–627.CrossRefGoogle Scholar
Zhang, Q., Xu, H., Yan, W., Nanoscience and Nanotechnology Letters 4 (2012) 505–519.CrossRefGoogle Scholar
Yoriya, S., Grimes, C.A., Langmuir 26 (2009) 417–420.CrossRefGoogle Scholar
Hahn, R., Schmidt‐Stein, F., Salonen, J., Thiemann, S., Song, Y.Y., Kunze, J., Lehto, V.P., Schmuki, P., Angewandte Chemie 121 (2009) 7372–7375.CrossRefGoogle Scholar
Albu, S.P., Ghicov, A., Macak, J.M., Schmuki, P., Physica Status Solidi (RRL)-Rapid Research Letters 1 (2006) R65–R67.CrossRefGoogle Scholar