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Electrical Conductivity and Raman Studies of B2O3-Na2O-NaI Glass Systems

Published online by Cambridge University Press:  16 February 2011

Byoung-Koo Choi ,
Kyoung-Hee Shin  and
Hyo-Kyoung Lee
Byoung-Koo Choi
Affiliation:
Department of science education, Dankook University, Yongsan, Seoul 140–714, Korea
Kyoung-Hee Shin
Affiliation:
Department of science education, Dankook University, Yongsan, Seoul 140–714, Korea
Hyo-Kyoung Lee
Affiliation:
Department of science education, Dankook University, Yongsan, Seoul 140–714, Korea
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Abstract

Glasses of B2O3-Na2O-Na2I2 have been prepared over a wide range of compositions on the basis of a fixed O/B ratio and a fixed Na/B ratio, respectively. Raman spectra and the ionic conductivity have been measured to elucidate the role of the iodide. In the fixed O/B ratio, a drastic increase of the conductivity with the addition of iodide is observed. The conductivity results are found to be consistent with the Raman results. In the fixed Na/B ratio, the substitution of iodide does not influence significantly the glass structure as well as the ionic conductivity.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 369: Symposium U – Solid State Ionics IV , 1994 , 469
Copyright
Copyright © Materials Research Society 1995

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References

references

1. Tuller, H.L., Button, D.P. and Uhlmann, D.R., J. Non-Cryst. Solids, 40, 93 (1980).Google Scholar
2. Levasseur, A., Brethous, J.C., Reau, J.M., Couzi, M. and Hagenmuller, P., Solid State Ionics, 1, 177 (1980).Google Scholar
3. Balkanski, M., Wallis, R.F., Deppe, J. and Massot, M., Mat. Sci. Eng. B, 12, 281 (1992) and references therein.Google Scholar
4. Irion, M. and Couzi, M., Levasseur, A., Reau, J.M. and Brethous, J.C., J. Solid St. Chem. 31, 285 (1980).Google Scholar
5. Soppe, W., Kleerebezem, J. and Hartog, H.W., J. Non-Cryst. Sol. 93, 142 (1987).Google Scholar
6. Massot, M., Haro, E., Oueslati, M. and Balkanski, M., in Solid State Ionics, edited by Nazri, G., Huggins, R.A. and Shriver, D.F. (Mater. Res. Soc. Proc. 135, Pittsburgh, PA, 1989) pp. 207–217.Google Scholar
7. Wang, Y., Osaka, A., Miura, Y. and Takahashi, K., J. Non-Cryst. Solids, 95&96, 571 (1987).Google Scholar
8. Turcotte, D.E., Risen, W.M. Jr. and Kamitos, E.I., Solid State Commun. 51, 313 (1984).Google Scholar
9. Chryssikos, G.D., Kamitos, E.J. and Karakassides, M.A., Phys. Chem. Glasses, 30, 243, 1989.Google Scholar
10. Geissberger, A.E., Bucholtz, F. and Bray, P.J., J. Non-Cryst. Solids, 49, 117 (1982).Google Scholar
11. Button, D.P., Tandon, R.P., King, C., Velez, M.H. and Tuller, D.R., J. Non-Cryst. Solids, 49, 129 (1982).Google Scholar
12. Konijnendijk, W.L. and Stevels, J.M., J. Non-Cryst. Solids, 18, 307 (1975).Google Scholar
13. Kamitos, E.L., Chryssikos, G.D., J. Molecular Structure, 247, 1 (1991).Google Scholar
14. Meera, B.N. and Ramakrishna, J., J. Non-Cryst. Solids, 159, 1 (1993) and references therein.Google Scholar
15. Bril, T.W., Philips Res. Rep. Suppl. No. 2, 111 (1976).Google Scholar
16. Wang, Y., Osaka, A., Miura, Y. and Takahashi, K., J. Mater. Res. 2, 606 (1987).Google Scholar
17. Fusco, F.A., Tuller, H.L. and Button, D.P., Materials Sci. and Eng. B, 13, 157 (1992).Google Scholar
18. Shelby, J.E. and Ortolano, R.L., Phys. Chem. Glasses, 31, 25 (1990).Google Scholar