Hostname: page-component-7479d7b7d-rvbq7 Total loading time: 0 Render date: 2024-07-08T09:09:35.057Z Has data issue: false hasContentIssue false

Electrical Characteristics of Thermal Spray Silicon Coatings

Published online by Cambridge University Press:  10 February 2011

S.Y. Tan
Affiliation:
Department of Materials Science and Engineering, SUNY at Stony Brook, 11794-2275
R.J. Gambino
Affiliation:
Department of Materials Science and Engineering, SUNY at Stony Brook, 11794-2275
R. Goswami
Affiliation:
Department of Materials Science and Engineering, SUNY at Stony Brook, 11794-2275
S. Sampath
Affiliation:
Department of Materials Science and Engineering, SUNY at Stony Brook, 11794-2275
H. Herman
Affiliation:
Department of Materials Science and Engineering, SUNY at Stony Brook, 11794-2275
Get access

Abstract

Polycrystalline silicon deposits were formed on a monocrystalline silicon substrate by thermal spraying. The resulting structure exhibits a device characteristic. Pressure-induced transformations of silicon, namely, Si-III (BC-8) and Si-IX are identified by X-ray diffraction in a Si-I matrix on deposits formed by vacuum plasma spray. The presence of the Si-III and Si-IX indicates that the pressure-quenched silicon deposit is highly conductive, as determined by four-point van der Pauw resistivity measurement. Hall mobility measurements, combined with photoconductivity results, indicate that the highly conductive silicon deposit displays the same range of mobility as a polycrystalline deposit containing only Si-I. The silicon deposit, with or without metastable phases, displays the same photoconductivity properties. The silicon deposit on a monocrystalline silicon substrate exhibits rectifying I–Vcharacteristics, possibly caused by band bending of trapping states associated with impurities segregating at the polycrystalline deposit/monocrystalline substrate interface

Type
Research Article
Copyright
Copyright © Materials Research Society 2000

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1 Duclos, S.J., Vohra, Y.K. and Ruoff, A.L., Phys. Rev. Lett. 58, 775 (1987).Google Scholar
2 McMahon, M.I. and Nelmes, R.J., Phys. Rev. B 47, 8337 (1993).Google Scholar
3 Zhao, Y.X., Buehler, F., Sites, J.R. and Spain, I.L., Solid State Comm. 59, 679 (1986).Google Scholar
4 Wentorf, R.H. and Kasper, J.S., Science 139, 338 (1963).Google Scholar
5 Besson, J.M., Mokhtari, E.H., Gonzalez, J. and Weill, G., Phys. Rev. Lett. 59, 473 (1987).Google Scholar
6 Goswami, R., Parise, J.B., Sampath, S. and Herman, H., J. Mater. Res. 14, 3489 (1999).Google Scholar
7 Tan, S.Y., Gambino, R.J. Goswami, R., Sampath, S. and Herman, H.. (to be published).Google Scholar
8 Houben, J.M., in Proc. 2nd National Thermal Spray Conf., Long Beach, CA (ASM, Metals Park, OH, 1984), p. 1.Google Scholar
9 Seto, J.Y.W., J. Appl. Phys. 46, 5247 (1975).Google Scholar
10 Tyagi, M.S., in Metal-Semiconductor Schottky Barrier Junctions and Their Applications, edited by Sharma, B.L. (Plenum Press, New York, 1984), p. 8.Google Scholar
11 Herman, H. and Sampath, S., Metallurgical and Ceramic Protective Coatings, (Chapman and Hall, London, 1996), p. 261.Google Scholar
12 Mailhot, K., Gitzhofer, F., and Boulos, M.I., in Proc. 15th International Thermal Spray Conf., Nice, France (1998) 1419.Google Scholar
13 Smits, F.M., Bell Syst. Tech. J. 41, 387 (1962).Google Scholar
14 Blood, P. and Orton, J.W., The Electrical Characterization of Semiconductors: Majority Carriers and Electron States, (Academic Press, London, 1992), p. 109.Google Scholar
15 Sze, S.M., Physics of Semiconductor Devices, (Wiley, New York, 1981), p. 756.Google Scholar
16 Tan, T.Y., Foll, H. and Hu, S.M., Philosophical Magazine A 44, 127 (1981).Google Scholar
17 Suryanarayanan, R. and Zribi, G., Journal de Physique. Colloque C–1, 375 (1982).Google Scholar
18 Kamins, T., Polycrystalline Silicon for Integrated Circuits, 2nd ed. (Kluwer Academic Press, Bosten, 1998), p. 208.Google Scholar
19 Orton, J.W., Goldsmith, B.J., Chapman, J.A. and Powell, M.J., J. Appl. Phys. 53, 1602 (1982).Google Scholar
20 Orton, J.W., and Powell, M.J., Rep. Prog. Phys. 43, 1263 (1980).Google Scholar
21 Stievenard, D. and Deresmes, D., Appl. Phys. Lett. 67, 1570 (1995).Google Scholar
22 Bube, R.H., Benatar, L.E., Grimbergen, M.N. and Redfield, D., J. Appl. Phys. 72, 5766 (1992).Google Scholar