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Effect of Power on the Properties of SiO2 Films Produced by Plasma-Enhanced Chemical Vapour Deposition

Published online by Cambridge University Press:  22 February 2011

Y. Tao
Affiliation:
Institute for Microstructural Sciences, National Research Council of Canada, Ottawa, Ontario, Canada K1A 0R6
D. Landheer
Affiliation:
Institute for Microstructural Sciences, National Research Council of Canada, Ottawa, Ontario, Canada K1A 0R6
J.-M. Baribeau
Affiliation:
Institute for Microstructural Sciences, National Research Council of Canada, Ottawa, Ontario, Canada K1A 0R6
J. E. Hulse
Affiliation:
Institute for Microstructural Sciences, National Research Council of Canada, Ottawa, Ontario, Canada K1A 0R6
D.-X. Xu
Affiliation:
Institute for Microstructural Sciences, National Research Council of Canada, Ottawa, Ontario, Canada K1A 0R6
M. J. Graham
Affiliation:
Institute for Microstructural Sciences, National Research Council of Canada, Ottawa, Ontario, Canada K1A 0R6
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Abstract

The effect of power on the properties of SiO2 films produced by direct plasma-enhanced chemical vapor deposition using nitrous oxide and silane with high helium dilution has been investigated. As the power increases the p-etch rate decreases while the frequency of the Si-O-Si stretching vibration measured by Fourier transform infra-red spectroscopy increases. However the refractive index of the films measured by ellipsometry is almost constant as is the electron density measured by low-angle x-ray reflection, indicating that the structural changes of the film with power do not relate to bulk density changes. The x-ray and ellipsometry measurements indicate the existence of a transitional layer with monolayer dimensions at the Si/SiO2 interface.

Type
Research Article
Copyright
Copyright © Materials Research Society 1994

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References

REFERENCES

1. Batey, J. and Tierney, E., J. Appl. Phys. 60, 3136 (1986); J. Batey, E. Tierney and T.N. Nguyen, IEEE Electron. Dev. Lett. EDL-8, 148 (1987).Google Scholar
2. Chaple-Sokol, J. D., Pliskin, W.A., Conti, R.A., Tierney, E., and Batey, J., J. Electrochem. Soc 138 3723 (1991).Google Scholar
3. Wang, L. K., Wen, D.S., Bright, A.A., Nguyen, T.N., and Chang, W., in 1989 IEDM Proceedines, (IEEE, New York, 1989), p.463.Google Scholar
4. Bright, A.A., Batey, J., and Tierney, E., Appl. Phys. Lett. 58, 6189 (1991).Google Scholar
5. Hattangady, S.V., Alley, R.G., Fountain, G.G., Markunas, R.J., Lucovsky, G., and Temple, D., J. Appl. Phys 73, 7635 (1993).Google Scholar
6. Lucovsky, G., Mantini, M.J., Srivastava, J.K., and Irene, E.A., J. Vac. Sci. Technol. B5, 530 (1987).Google Scholar
7. Pai, P.G., Chao, S.S., Takagi, Y., and Lucovsky, G., J. Vac. Sci. Technol. A4, 690 (1969).Google Scholar
8. Pliskin, W.A. in Semiconductor Silicon edited by Huff, H.R. and Burgess, R.R., in Electrochem. Soc. Softbound Proceeding Series, (Princeton, NJ, 1973), p. 506.Google Scholar
9. Aspnes, D.E. and Studna, A.A., Rev. Sci. Instrum. 49, 291 (1978).Google Scholar
10. Paratt, L.G., Phys. Rev. 95, 359 (1954).Google Scholar
11. Aspnes, D.E. and Theeten, J.B., J. Electrochem. Soc. 127, 1359 (1980).Google Scholar
12. Hulse, J.E., Bardwell, J.A., Clark, K.B., Hussey, R.J., Landheer, D. and Rolfe, S.J., (unpublished).Google Scholar
13. Malitson, I. H., J. Opt. Soc. Am. 55, 1205 (1965).Google Scholar
14. Bruggeman, D. A. G., Ann. Phys. (Leipzig) 24, 636 (1935).Google Scholar
15. Jellison, G.E. Jr, Opt. Mater. 1, 41 (1992).Google Scholar
16. Plieth, W. J. and Naegele, K., Surf. Sci. 64, 484 (1977).Google Scholar
17. Dignam, M.J. and Moskovits, M., J. Chem. Soc. Faraday II 69, 56 (1973).Google Scholar
18. Heald, S.M., Jayanetti, J.K.D., Bright, A.A. and Rubloff, G.W., J. Vac. Sci. Technol. A8, 2046(1990).Google Scholar