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Effect of Ca and Ag doping on the functional properties of BiFeO3 nanocrystalline powders and films

Published online by Cambridge University Press:  04 August 2014

Gina Montes Albino ,
Oscar Perales-Pérez ,
Boris Renteria-Beleño  and
Yarilyn Cedeño-Mattei
Gina Montes Albino
Affiliation:
Department of Mechanical Engineering, University of Puerto Rico at Mayagüez P.O. Box 9045, Mayagüez, PR, 00681-9045 USA.
Oscar Perales-Pérez
Affiliation:
Department of Engineering Science and Materials, University of Puerto Rico at Mayagüez, Mayagüez, PR, 00680-9044, USA.
Boris Renteria-Beleño
Affiliation:
Department of Engineering Science and Materials, University of Puerto Rico at Mayagüez, Mayagüez, PR, 00680-9044, USA.
Yarilyn Cedeño-Mattei
Affiliation:
Department of Engineering Science and Materials, University of Puerto Rico at Mayagüez, Mayagüez, PR, 00680-9044, USA.
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Abstract

The present work addresses the systematic evaluation of the influence of the incorporation of dopant species (Ca+2, Ag+1) on the structural and functional properties of bismuth ferrite (BFO) nanocrystalline powders and films. Pure and doped BFO powders and thin films were synthesized by a modified sol-gel method. The concentration of the doping species varied from 0 up to 7 at %. The development of the host BFO structure was confirmed by XRD analyses of samples annealed at 700°C for one hour in air and nitrogen atmosphere. Thicknesses of films varied between 80 and 200 nm, depending on the concentration of Ca+2 species. Doped BFO exhibited a magnetic behavior that turned from paramagnetic into ferrimagnetic with the increase of Ca+2 concentrations.

Keywords

sol-gelmagnetic propertiesgrain size
Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1675: Symposium K/RR – Synthesis, Characterization and Applications of Functional Materials— Thin Films and Nanostructures , 2014 , pp. 105 - 111
Copyright
Copyright © Materials Research Society 2014 

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References

REFERENCES

Zhang, S.-T.; Pang, L.-H.; Zhang, Y.; Lu, M.-H.; Chen, Y.-F. J. Appl. Phys. 2006, 100, 114108.CrossRefGoogle Scholar
Yuan, G. L.; Or, S. W.; Chan, H. L. W. J. Phys. D: Appl. Phys. 2007,40, 1196–1200.CrossRefGoogle Scholar
Mathe, V. L.; Patankar, K. K.; Patil, R. N.; Lokhande, C. D. J. Magn. Magn. Mater. 2004, 270, 380–388 CrossRefGoogle Scholar
Yuan, G. L.; Or, S. W.; Liu, J. M.; Liu, Z. G. Appl. Phys. Lett. 2006,89, 052905.Google Scholar
Mathe, V. L. J. Magn. Magn. Mater. 2003, 263, 344–352.CrossRefGoogle Scholar
Yuan, G. L.; Or, S. W. J. Appl. Phys. 2006, 100, 024109.Google Scholar
Wang, D. H.; Goh, W. C.; Ning, M.; Ong, C. K. Appl. Phys. Lett.2006, 88, 212907.CrossRefGoogle Scholar
Li, J.; Duan, Y.; He, H.; Song, D. J. Alloys Compd. 2001, 315, 259–264.CrossRefGoogle Scholar
Khomchenko, V. A.; Kiselev, D. A.; Vieira, J. M.; Kholkin, A. L.;Sa, M. A.; Pogorelov, Y. G. Appl. Phys. Lett. 2007, 90, 242901.CrossRefGoogle Scholar
Kothari, D.; Reddy, V. R.; Gupta, A.; Sathe, V.; Banerjee, A.; Gupta, S. M.; Awasthi, A. M. Appl. Phys. Lett. 2007, 91, 202505.CrossRefGoogle Scholar
Yu, B.; Li, M.; Liu, J.; Guo, D.; Pei, L.; Zhao, X. J. Phys. D: Appl. Phys. 2008, 41, 065003.Google Scholar
Jun, Y.-K.; Moon, W.-T.; Chang, C.-M.; Kim, H.-S.; Ryu, H. S.; Kim, J. W.; Kim, K. H.; Hong, S.-H. Solid State Commun. 2005, 135, 133–137.CrossRefGoogle Scholar
Yang, C. H.; Koo, T. Y.; Jeong, Y. H. Solid State Commun. 2005,134, 299–301.CrossRefGoogle Scholar
Santos, I. A.; Grande, H. L. C.; Freitas, V. F.; de Medeiros, S. N.;Paesano, J. A.; Co´tica, L. F.; Radovanovic, E. J. Non-Cryst. Solids 2006, 352, 3721–3724.CrossRefGoogle Scholar
Qi, X.; Dho, J.; Tomov, R.; Blamire, M. G.; MacManus-Driscoll, J. L. Appl. Phys. Lett. 2005, 86, 062903.Google Scholar
Bhushana, B., Das, D., Priyamc, A. Vasanthacharya, N.Y., Kumar, S.; Materials Chemistry and Physics 135 (2012) 144–149 CrossRefGoogle Scholar
Huang, Ji-Zhou, Shen, Yang, Li, Ming,and Nan, Ce-Wen: JOURNAL OF APPLIED PHYSICS 110, 094106 (2011).Google Scholar
Rubia, D., Marlascaa, F.G., Reinosoa,b, M., Bonvilled, P., Levy, P.; Materials Science and Engineering B 177 (2012) 471–475 CrossRefGoogle Scholar
Ahmeda, M.A., Mansour, S.F., El-Deka, S.I., Abu-Abdeenc, M.; Materials Research Bulletin 49 (2014) 352–359 CrossRefGoogle Scholar
Maso, Nahum and West, Anthony R.; Chem. Mater. 2012, 24, 2127–2132 CrossRefGoogle Scholar