Hostname: page-component-586b7cd67f-t7czq Total loading time: 0 Render date: 2024-11-25T15:42:11.699Z Has data issue: false hasContentIssue false
  • English
  • Français

Domain-Spatial Correlation Function of Spherulitic Domain Evolution in Polymer Films

Published online by Cambridge University Press:  10 February 2011

Tao Huang ,
Tomohiro Tsuji ,
M. R. Kamal  and
A. D. Rey
Tao Huang
Affiliation:
Department of Chemical Engineering, McGill University, 3610 University Street, Montreal, Quebec, Canada, H3A [email protected]
Tomohiro Tsuji
Affiliation:
Department of Chemical Engineering, McGill University, 3610 University Street, Montreal, Quebec, Canada, H3A [email protected]
M. R. Kamal
Affiliation:
Department of Chemical Engineering, McGill University, 3610 University Street, Montreal, Quebec, Canada, H3A [email protected]
A. D. Rey
Affiliation:
Department of Chemical Engineering, McGill University, 3610 University Street, Montreal, Quebec, Canada, H3A [email protected]
Get access

Abstract

We present a new theoretical model of nucleation and growth in term of a novel domainspatial correlation function. This model probes the patterns and spatio-temporal evolution of nucleation and growth process and agrees very well with experimental data. The dynamic domain-spatial correlation function directly and simultaneously explores the transformed volume fraction, the time-dependent domain size distribution function, and the spatial correlation function of domain core centers for the entire process, including the post-nucleation, domain growth and grain formation stages.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 481: Symposium P – Science and Technology of Semiconductor Surface Preparation , 1997 , 131
Copyright
Copyright © Materials Research Society 1998

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Gunton, J.D., Miguel, M.S. and Sahni, P., in Phase Transitions and Critical Phenomena, edited by Domb, C. and Lebowitz, J.L., (Academic Press, London, 1983), Vol: 8, p. 267;Google Scholar
2. Kolmogorov, A.N., Izv. Akad. Nauk SSSR, Ser. Matem No. 3, 355–359 (1937); W. Johnson and R.F. Mehl, TAIME 135, 416 (1939); M. Avrami, J. Chem. Phys. 7, 1103 (1939), 212 (1940), 177 (1941); J.W. Cahn, Mat. Res. Soc. Symp. Proc. Vol.398, p.425, 1996 Materials Research Society.Google Scholar
3. Sekimoto, K., Phys. Lett. A 105 390 (1984); J. Phys. Soc. Jpn.53 2425 (1984); Physica A 137 96 (1986);Google Scholar
4. Axe, J.D. and Yamada, Y., Phys. Rev. B 34, 1599 (1986); S. Ohta, T. Ohta and K. Kawasaki, Physica A 140, 478 (1987).Google Scholar
5. Stoyan, D. and Kendall, W.S., Stochastic Geometry and Its Applications, (J. Weiley, NY, 1995).Google Scholar