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Dielectric Properties of Electrostatic Self-Assembled (ESA) Films

Published online by Cambridge University Press:  01 February 2011

Ramazan Asmatulu ,
Brian Geist ,
William B. Spillman Jr  and
Richard O. Claus
Ramazan Asmatulu
Affiliation:
Virginia Tech Applied Biosciences Center, 106 Plantation Road, Virginia Polytechnic Institute and State University 0356, Blacksburg VA 24061
Brian Geist
Affiliation:
Virginia Tech Applied Biosciences Center, 106 Plantation Road, Virginia Polytechnic Institute and State University 0356, Blacksburg VA 24061
William B. Spillman Jr
Affiliation:
Virginia Tech Applied Biosciences Center, 106 Plantation Road, Virginia Polytechnic Institute and State University 0356, Blacksburg VA 24061
Richard O. Claus
Affiliation:
Virginia Tech Applied Biosciences Center, 106 Plantation Road, Virginia Polytechnic Institute and State University 0356, Blacksburg VA 24061
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Abstract

Capacitance measurements were conducted to determine the dielectric constant of electrostatic self assembly (ESA) films over various temperature and frequency ranges at 1 mV and 15% relative humidity. Measurement electrodes were fabricated on the ESA films using silver grease and a brass bar. In these tests, polymeric nanofilms were fabricated on gold-coated glass slides using the ESA process. Thicknesses of the films were between 100 nm and 600 nm obtained by depositing different number bilayers of negatively charged Poly s-119 (PS-119) or heparin and positively charged poly(diallyldimethylammonium chloride) (PDDA). The test results showed that dielectric constant values were around 2. Based on the test results, we concluded that this is a technique that might prove useful to estimate the capacitance and dielectric constant values of nanostructured ESA films, which can be largely used in the near future.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 871: Symposium I – Organic Thin-Film Electronics , 2005 , I9.2
Copyright
Copyright © Materials Research Society 2005

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References

1 Decher, G. and Schlenoff, J.B. “Multilayers Thin Films – Sequential Assembly of Nanocomposite Materials,” Wiley-VCH, 2003.Google Scholar
2 Liu, Y., Wang, A. and Claus, R., J. Physical Chemistry B 1997, 101, 1385–1388.Google Scholar
3 Liu, Y. and Claus, R., Appl. Phys. Lett. 85, 419 (1999).Google Scholar
4 Chandran, A. “Self-assembled Spectral Filters,” Unpublished data, FEORC, Virginia Tech.Google Scholar
5 Liu, Y., Wang, A. and Claus, R., Chemical Physics Letters 298(1998) 315–319.Google Scholar
6 Asmatulu, R., Geist, B. Spillman, W., and Claus, R.O., March, 2005, SPIE, V. 5761, 31–39.Google Scholar
7 Asmatulu, R., Geist, B. Spillman, W., and Claus, R.O., Unpublished data, FEORC, Virginia Tech, Blacksburg, VA.Google Scholar
8 Nalwa, H.S. “Handbook of Low and High Dielectric Constant Materials and Their Applications – Materials and Processing – Vol. 1,” Academic Press, 1999.Google Scholar
9 Ho, P.S., Leu, J. and Lee, W.W. “Low Dielectric Constant Materials for IC Application,” Springer, 2003.Google Scholar
10 Callister, W.D. Jr “Materials Science and Engineering – an Introduction, 5th Ed.,” John Wiley & Sons, Inc., 2000.Google Scholar
11ASTM Designation: D 150-98.Google Scholar
12 Dakhel, A.A., Journal of Alloys and Compounds 365 (2004) 233.Google Scholar
13 Sahu, D.R., Roul, B.K., Singh, S.K. and Choudhury, R.N.P., Mater. Lett. 56 (2002) 817.Google Scholar
14 Velumani, S., , Narayandass, Mangalaraj, S.K. D., Sebastian, P.J. and Mathew, X., Solar Energy Materials & Solar Cells 81(2004) 323.Google Scholar
15 Wagle, S. and Shirodkar, V., Brazilian Journal of Physics, V. 30, No. 3, Sep. 2000, 554.Google Scholar
16 Mathai, C.J., Saravanan, S. Anantharaman, M.R., Venkitachalam, S. and Jayalekshmi, S., Journal of Physics D: Applied Physics 35(2002) 240.Google Scholar
17 Paddison, S.J., Reagor, D.W. and Zawodzinski, T.A. Jr , Journal of Electroanalytical Chemistry 459(1998) 91.Google Scholar
18 Day, J.S., Landis, R.C. and Taylor, K.M., J Cardiovasc & Vasc Anesthesia 18; 93–100, 2004 Google Scholar