Hostname: page-component-cd9895bd7-q99xh Total loading time: 0 Render date: 2024-12-27T02:10:50.341Z Has data issue: false hasContentIssue false

Dielectric and Ferroelectric Properties of Pulsed Laser Deposited Strontium Barium Niobate Thin Films

Published online by Cambridge University Press:  10 February 2011

Y. Liu
Affiliation:
Department of Applied Physics and Materials Research Center, The Hong Kong Polytechnic University, Hung Horn, Kowloon, Hong Kong
C.W. Ong
Affiliation:
Department of Applied Physics and Materials Research Center, The Hong Kong Polytechnic University, Hung Horn, Kowloon, Hong Kong
C.L. Choy
Affiliation:
Department of Applied Physics and Materials Research Center, The Hong Kong Polytechnic University, Hung Horn, Kowloon, Hong Kong
P.W. Chan
Affiliation:
Department of Applied Physics and Materials Research Center, The Hong Kong Polytechnic University, Hung Horn, Kowloon, Hong Kong
Get access

Abstract

The dielectric and ferroelectric properties of pulsed laser deposited strontium barium niobate (SBN) thin films were investigated. The samples were prepared using a Q-switched Nd:YAG laser with a wavelength of 355 nm and a fluence of 8 J cm−2. The oxygen ambient pressure and substrate temperature were set at 50 mTorr and 700 °C, respectively. The measurements of x-ray diffraction show that the films have tungsten-bronze- type structure. Pt/SBN/Pt capacitor structure was made on (111) silicon wafer to perform the ferroelectric and dielectric measurements. From the observations of the P-E loops, the saturation polarization, remanent polarization and coercive field at 25°C are equal to 40.7 μC cm−2, 32.5 μC cm−2 and 3.8 kV cm−1. The shape of the P-E loop becomes slimmer at temperatures above 150 °C, indicating that a ferroelectric-to-paraelectric transition occurs. The dielectric constant and loss tangent of the films at 10 kHz were found to be equal to 240 and 0.4, respectively. The saturation and remanent polarization remain almost unchanged after 109 switching cycles, indicating that pulsed laser deposited SBN films have good fatigue endurance.

Type
Research Article
Copyright
Copyright © Materials Research Society 1996

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Sakamoto, S. and Yazaki, T., Appl. Phys. Lett. 22, 429 (1973).Google Scholar
2. Micheron, F. and Bismuth, G., Appl. Phys. Lett. 23, 71(1973).Google Scholar
3. Zook, J.D. and Liu, S.T., J. Appl. Phys. 49, 4604 (1978).Google Scholar
4. Lu, Z., Feigelson, R.S., Route, R.K., Hiskes, R., and Dicarolis, S.A., Mater. Res. Roc. Symp. Proc. 335, 59 (1993).Google Scholar
5. Neurgaonkar, R.R. and Wu, E.T., Mater. Res. Bull. 22, 1095 (1987).Google Scholar
6. Xu, Y., Chen, C.J., Xu, R., and Mackenzie, J. D., Ferroelectrics 108, (1990).Google Scholar
7. Wu, A.Y., Wang, F., Juang, C.-B., Bustamante, C., Yeh, H.-Y., and Diels, J.C., IEEE 7th International Symposium on Applications of Ferroelectrics, 1990, pp. 135.Google Scholar
8. Thony, S.S., Youden, K.E., Harris, J.S. Jr.,, and Hesselink, L., Appl. Phys. Lett. 65, 2018 (1994).Google Scholar
9. Liu, Y., Ong, C.W., Chan, P.W. and Choy, C.L., Mat. Res. Soc. Symp. Proc. 316, 557 (1995).Google Scholar
10. Maciolek, R.B. and Liu, S.T., J. Electron. Mater. 2, 191 (1973).Google Scholar
11. Chen, C.J., Xu, Y., Xu, R. and Mackezie, J.D., J. Appl. Phys. 69, 47, 1763 (1991).Google Scholar
12. Deshpande, S.B., Potdar, H.S., Godbole, P.D. and Date, S.K., J.Am. Ceram Soc. 75, 2581 (1992).Google Scholar
13. Ballman, A.A. and Brown, H., J. Cryst. Growth 1, 311 (1967).Google Scholar
14. Jones, L., Bridger, K., Chen, C.L., Ritter, K., Sutherland, A. E., VanDamme, N.S. and Winzer, S.R., IEEE 7th International Symposium on Applications of Ferroelectrics, 1990, pp.627.Google Scholar