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Determination of Inelastic Mean Free Path by Electron Energy-Loss Spectroscopy in TEM: A Model Study Using Si and Ge

Published online by Cambridge University Press:  01 February 2011

Chongmin Wang  and
Bret D. Cannon
Chongmin Wang
Affiliation:
[email protected], Pacific Northwest National Laboratory, Environmental Molecular Science Laboratory, 3335 Q Ave, MSIN: K8-93, Richland, WA, 99354, United States, (509) 3764292
Bret D. Cannon
Affiliation:
[email protected], Pacific Northwest National Laboratory, Richland, WA, 99352, United States
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Abstract

Although the inelastic mean free path for Si and Ge have been measured previously, reported experimental values for silicon range from 121 nm to 160 nm for 200 keV and a large collection angle. A key factor responsible for this uncertainty is the lack of an accurate measurement of the specimen thickness at the point at which the EELS spectra are obtained. In this research, we have evaluated a systematic methodology for determination of the specimen thickness. In the thickness measurement based on converging beam electron diffraction, CBED, instead of the classic “trial and error” straight-line-fitting method to either the maxima or minima, a non-linear least square fitting of the theoretical diffraction profile to the energy filtered two-beam CBED is used. The low-loss EELS spectrum is also obtained from the same location. The inelastic mean free path was determined using the measured thickness and EELS data. Furthermore, attempt is also made to obtain the dielectric function from the low-loss spectrum. The established method will be extended to other materials and the results will be compared with numerical simulations.

Keywords

electron energy loss spectroscopy (EELS)SiGe
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 982: Symposium KK – Electron Microscopy Across Hard and Soft Materials , 2006 , 0982-KK07-13
Copyright
Copyright © Materials Research Society 2007

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