Hostname: page-component-cd9895bd7-gvvz8 Total loading time: 0 Render date: 2024-12-27T02:08:34.658Z Has data issue: false hasContentIssue false

The Design of Candidate Optical Limiters

Published online by Cambridge University Press:  15 February 2011

Ruth Pachter
Affiliation:
Materials Directorate, Wright Laboratory, Wright-Patterson Air Force Base, Ohio 45433
Robert L. Crane
Affiliation:
Materials Directorate, Wright Laboratory, Wright-Patterson Air Force Base, Ohio 45433
W. Wade Adams
Affiliation:
Materials Directorate, Wright Laboratory, Wright-Patterson Air Force Base, Ohio 45433
Get access

Abstract

Series of molecules and polymeric systems are being evaluated as optical limiters for the design of a high second molecular hyperpolarizability γ. For example, results for a series of tolanes are discussed, as well as those of semi-flexible, stiff-chain polymers, including substituted biphenyl (X, Y = H, CH3, NO2, or a halogen atom) and benzo-bisthiazole moieties. The non-linear optical response was calculated using a finite field approach and compared for various derivatives.

Type
Research Article
Copyright
Copyright © Materials Research Society 1995

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Burland, D.M., Chemical Reviews 94, 1 (1994).Google Scholar
2. Bredas, J.L., Adant, C., Tackx, P., and Pearsons, A., Chemical Reviews 94, 243 (1994).Google Scholar
3. Day, P., Wang, Z., Pachter, R., et al., J. Phys. Chem., submitted; Z. Wang., P. Day, R. Pachter, et al., Chem. Phys. Lett., submitted.Google Scholar
4. Cooper, T.M., Natarajan, L.V., Strasser, R., Pachter, R., and Crane, R.L., ACS Polymer Preprint 33, 669 (1992)Google Scholar
5. Pachter, R., Cooper, T.M., Natarajan, L.V., Obermeier, K., Crane, R.L., and Adams, W.W., Biopolymers 32, 1129 (1992).Google Scholar
6. Jensen, J.H., Day, P. Gordon, M.S.,, Basch, H., Cohen, D., Garmer, D.R., Kraus, M., Stevens, W.J., In: Modeling the Hydrogen Bond, ed. Smith, Douglas A., ACS Symposium Series 569, 139 (1994).Google Scholar
7. McLean, D.G., Sutherland, R.L., Brandt, M.C., Brandelik, D.M., and Pottenger, T., Opt. Lett. 18, 858 (1993).Google Scholar
8. Wang, Z.., Day, P., Pachter, R., et al., manuscript in preparation.Google Scholar
9. Shelton, D.P. and Rice, J.E., Chemical Reviews 94, 3 (1994).Google Scholar
10. Natarajan, L.V., Bunning, T.J., Pachter, R., Patnaik, S.S., Crane, R.L., and Adams, W.W., The 2nd International Symposium on Chemistry of Functional Dyes Symposium Proceedings, Kinki Chemical Society & Japanese Chemical Society 2, 405 (1992).Google Scholar
11. Viney, C., Brown, D.J., Dannels, C.M., and Twieg, R.J., Liquid Crystals 13, 95 (1993).Google Scholar
12. Fleitz, P.A., McLean, D.G., and Sutherland, R.L., SPIE Proceedings, 2229, 33 (1994).Google Scholar
13. Saebo, S., Almlof, J., Boggs, J. E., and Stark, J. G., J. Mol. Struct. (THEOCHEM) 200 361 (1989).Google Scholar
14. Stolevik, R. and Bakken, P., J. Mol. Struct. 13, 79 (1972).Google Scholar
15. Kellerer, B. and Hacker, H.H., J. Mol. Struct. 239, 205 (1990).Google Scholar
16. Pachter, R., Adams, W.W., Hu, X., Polk, M.B., and Kumar, S., Abstract from the Spring Meeting of the Materials Research Society, San Francisco, California, April 1994.Google Scholar
17. Janekhe, S.A., Osaheni, J.A., Meth, J.A., and Vanherzeele, H., Che. Mater. 4, 683 (1992).Google Scholar
18. Kurtz, H., Stewart, A., , J.J.P. and Dieter, K. M., J. Comp. Chem. 11, 82 (1990).Google Scholar
19. Stewart, J.J.P., MOPAC '93, QCPE, 1992.Google Scholar
20. Goldfarb, H., Reale, S., Wierschke, S., and Medrano, J., The Materials Science and Engineering of Rigid Rod Polymers, Materials Research Society Symposium Proceedings 134, 609 (1989).Google Scholar
21. Matsuzawa, N. and Dixon, D.A., J. Phys. Chem. 96, 6232 (1992).Google Scholar
22. Paolini, J.H., J. Comp. Chem. 11, 1160 (1990).Google Scholar
23. Fleitz, P.A., Bunning, T.J., et al., work in progress.Google Scholar