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Design and Preparation of Heterogeneous Catalysts by Controlled Chemical Reactions with Oxygen and Hydrogen

Published online by Cambridge University Press:  15 February 2011

David L. Cocke ,
Donald G. Naugle  and
Thomas R. Hess
David L. Cocke
Affiliation:
Department of Chemistry, Gill Chair, Lamar University, Beaumont, TX 77710
Donald G. Naugle
Affiliation:
Department of Physics, Texas A&M University, College Station, TX 77843
Thomas R. Hess
Affiliation:
Department of Physics, Texas A&M University, College Station, TX 77843
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Abstract

Chemical reactions of metals and strongly interacting alloys such as Cu-Mn, Ni-Ti, Ni-Hf and Ni-Zr with oxygen and hydrogen play important roles in the preparation, activation, and regeneration of many important heterogeneous catalytic systems involving supported and unsupported metals and alloys. Recent advances in the understanding of metal and alloy oxidation is bringing new insight into the reactive design and activation of bi- and multi-metallic catalysts. By surface studies of oxidation, thermal annealing and reduction of selected alloys and their thin films and reaction layers and products we have been able to delineate the factors which are most important to the oxide formation processes and the oxide reduction processes. Reaction models developed from these results are permitting the design of new catalyst systems and providing long sought understanding to explain specific aspects of well established metallic catalysts.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 368: Symposium T – Synthesis and Properties of Advanced Catalytic Materials , 1994 , 121
Copyright
Copyright © Materials Research Society 1995

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References

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