Hostname: page-component-586b7cd67f-rdxmf Total loading time: 0 Render date: 2024-11-29T07:39:33.022Z Has data issue: false hasContentIssue false
  • English
  • Français

Defect Structure and Ion Transport in PbFCI

Published online by Cambridge University Press:  21 February 2011

M. Saiful Islam
M. Saiful Islam*
Affiliation:
Research Laboratories, Eastman Kodak Company, Rochester, NY 14650
Get access

Abstract

Theoretical techniques are used to examine the energetics of defect formation and ion transport mechanisms in PbFCI. Schottky disorder is found to be the dominant intrinsic defect. The calculated formation energy is in good agreement with experiment. Activation energies for the migration of anion vacancies are presented.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 135: Symposium M – Solid State Ionics I , 1988 , 295
Copyright
Copyright © Materials Research Society 1989

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Eijkelenkamp, A.J.H. and Vos, K., Phys. Stat. Sol. (b) 76, 769 (1976).Google Scholar
2. Eijkelenkamp, A.J.H., Solid State Commun. 18, 295 (1976); J. Solid State Chem. 19, 313 (1976).Google Scholar
3. Somaiah, K. and Moinuddrin, S. R., J. Mater. Sci. Lett. 6, 417 (1987).Google Scholar
4. Schoonman, J., Dirksen, G. J., and Blasse, G., J. Solid State Chem. 7, 245 (1973).Google Scholar
5. Halff, A.F. and Schoonman, J., Z. Phys. Chem. 109, 161 (1978); J. Solid State Chem. 27, 397 (1979).Google Scholar
6. Nieuwenkamp, W. and Bijvoet, J. M., Z. Krist. 81, 469 (1932); A.F. Wells, in Structural Inorganic Chemistry (Clarendon Press, Oxford, 1984).Google Scholar
7. Sommerdijk, J. L., Verstegen, J.M.P., and Bril, A., J. Lumin. 8, 502 (1974).Google Scholar
8. Takahashi, K., Kohda, K., Miyahara, J., Kanemitsu, Y., Amitani, K., and Shionoya, S., J. Lumin. 31, 266 (1984).Google Scholar
9. For example: Catlow, C.R.A., Norgett, M. J., and Ross, T. A., J. Phys. C 10, £1627 (1977); P. J. Bendall, C.R.A. Catlow, and B.E.F. Fender, J. Phys. C J., 4377 (1981); P.W.M. Jacobs, V.C. Sahni, and C.S. Vempati, Philos. Mag. A 49, 301 (1984).Google Scholar
10. Baetzold, R.C., Phys. Rev. B 36, 9182 (1987).Google Scholar
11. Leslie, M., Solid State Ionics Q, 243 (1983).Google Scholar
12. Catlow, C.R.A., James, R., Mackrodt, W.C., and Stewart, R.F., Phys. Rev. 25 1006 (1982).Google Scholar
13. Dick, B.G. and Overhauser, A.W., Phys. Rev. 112, 90 (1958).CrossRefGoogle Scholar
14. Catlow, C.R.A. and Mackrodt, W.C. (Eds.), Computer Simulation of Solids. Lecture Notes in Physics, Vol. 166 (Springer-Verlag, Berlin, 1982).Google Scholar
15. Catlow, C.R.A., Ann. Rev. Mater. Sci. 16, 517 (1986).Google Scholar
16. Baetzold, R.C. (to be published).Google Scholar