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Cu2ZnSnSe4 from Chemically Deposited Binary Films

Published online by Cambridge University Press:  01 August 2014

Enue Barrios-Salgado ,
José Campos ,
M. T. S. Nair  and
P. K. Nair
Enue Barrios-Salgado
Affiliation:
Instituto de Energías Renovables, Universidad Nacional Autónoma de México Temixco, Morelos-62580, México|
José Campos
Affiliation:
Instituto de Energías Renovables, Universidad Nacional Autónoma de México Temixco, Morelos-62580, México|
M. T. S. Nair
Affiliation:
Instituto de Energías Renovables, Universidad Nacional Autónoma de México Temixco, Morelos-62580, México|
P. K. Nair
Affiliation:
Instituto de Energías Renovables, Universidad Nacional Autónoma de México Temixco, Morelos-62580, México|
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Abstract

Chemically deposited thin film stack of SnSe-ZnSe-Cu2-xSe was heated in nitrogen with Se vapor at 350-400 oC to produce Cu2ZnSnSe4 (CZTSe) thin films. For this, a thin film of SnSe with 180 nm thickness was deposited at 26 °C from a chemical bath containing tin(II) chloride, triethanolamine, sodium hydroxide, sodium selenosulfate, and a small quantity of polyvinylpyrrolidone. Thin films of ZnSe and Cu2-xSe were subsequently deposited on this SnSe film, also from chemical bath. The CZTSe thin film produced this way shows X-ray diffraction pattern matching that of Cu2ZnSnSe4 (kesterite/stannite) and have a Zn-rich composition. The film has an optical band gap of 0.9-1.0 eV and p-type electrical conductivity, 0.2-0.06 Ω-1 cm-1.

Keywords

electronic materialfilmphotovoltaic
Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1670: Symposium E/H – Advances in the Characterization, Performance and Defect Engineering of Earth Abundant and Thin-Film Materials for Solar Energy Conversion , 2014 , mrss14-1670-e05-14
Copyright
Copyright © Materials Research Society 2014 

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References

Wibowo, Rachmat Adhi, Kim, Woo Seok, Lee, Eun Soo, Munir, Badrul, Kim, Kyoo Ho. Journal of Physics and Chemistry of Solids 68 (2007) 1908–1913 10.1016/j.jpcs.2007.05.022CrossRefGoogle Scholar
Salomé, P.M.P., Fernandes, P.A., da Cunha, A.F.. Thin Solid Films 517 (2009) 2531–2534 10.1016/j.tsf.2008.11.034CrossRefGoogle Scholar
Brammertz, Guy, Ren, Yi, Buffière, Marie, Mertens, Sofie, Hendrickx, Jurgen, Marko, Hakim, Zaghi, Armin E., Lenaers, Nick, Köble, Christine, Vleugels, Jef, Meuris, Marc, Poortmans, Jef. Thin Solid Films 535 (2013) 348–352.10.1016/j.tsf.2012.10.037CrossRefGoogle Scholar
Kuo, Dong-Hau, Hsu, Jen-Pin. Journal of Crystal Growth 372(2013)34–38 10.1016/j.jcrysgro.2013.03.013CrossRefGoogle Scholar
Wibowo, R.A., Lee, E.S., Munir, B., Kim, K.H.. Phys. Status Solidi A 204(2007) 3373–3379.10.1002/pssa.200723144CrossRefGoogle Scholar
Lee, Seung Min, Mohanty, Bhaskar Chandra, Jo, Yeon Hwa, Yeon, Deuk Ho, Cho, Yong Soo. Surface & Coatings Technology 231 (2013) 389–393 10.1016/j.surfcoat.2012.01.054CrossRefGoogle Scholar
Jung, Sunghun, Gwak, Jihye, Yun, Jae Ho, Ahn, SeJin, Namb, Dahyun, Cheong, Hyeonsik, Ahn, Seungkyu, Cho, Ara, Shin, Kee Shik, Yoon, Kyung Hoon. Thin Solid Films 535 (2013) 52–56 10.1016/j.tsf.2012.10.082CrossRefGoogle Scholar
Kaune, Gunar, Hartnauer, Stefan, Syrowatka, Frank, Scheer, Roland. Solar Energy Materials and Solar Cells, Volume 120, Part B, January 2014, Pages 596–602 10.1016/j.solmat.2013.09.043CrossRefGoogle Scholar
Redinger, Alex, Mousel, Marina, Wolter, Max Hilaire, Valle, Nathalie, Siebentritt, Susanne. Thin Solid Films 535 (2013) 291–295 10.1016/j.tsf.2012.11.111CrossRefGoogle Scholar
Repins, I. L., Beall, C., Vora, N., Dehart, C., Kuciauskas, D., Dippo, P., To, B., Goodrich, A., and Noufi, R., “Co-evaporated Cu2ZnSnSe4 Films and Devices,” Sol. Energy Mater. Sol. Cells, vol. 101, pp. 154–159, 2012.10.1016/j.solmat.2012.01.008CrossRefGoogle Scholar
Suresh Babu, G., Kishore Kumar, Y.B., Uday Bhaskar, P., Sundara Raja, V.. Solar Energy Materials and Solar Cells 94 (2010) 221–226.10.1016/j.solmat.2009.09.005CrossRefGoogle Scholar
Uday Bhaskar, P., Suresh Babu, G., Kishore Kumar, Y.B., Sundara Raja, V.. Solar Energy Materials & Solar Cells115(2013)181–188 10.1016/j.solmat.2013.03.017CrossRefGoogle Scholar
Volobujeva, O., Bereznev, S., Raudoja, J., Otto, K., Pilvet, M., Mellikov, E.. Thin Solid Films 535 (2013) 48–51 10.1016/j.tsf.2012.12.080CrossRefGoogle Scholar
Kim, SeongYeon, Kim, JunHo. Thin Solid Films 547 (2013) 178–180 10.1016/j.tsf.2013.03.094CrossRefGoogle Scholar
Meng, Mingming, Wan, Lei, Zou, Peng, Miao, Shiding, Xu, Jinzhang. Applied Surface Science 273 (2013) 613– 616 10.1016/j.apsusc.2013.02.088CrossRefGoogle Scholar
Iljina, J., Volobujeva, O., Raadik, T., Revathi, N., Raudoja, J., Loorits, M., Traksmaa, R., Mellikov, E.. Thin Solid Films 535 (2013) 14–17 10.1016/j.tsf.2012.12.085CrossRefGoogle Scholar
Septina, Wilman, Ikeda, Shigeru, Kyoraiseki, Akio, Harada, Takashi, Matsumura, Michio. Electrochimica Acta 88 (2013) 436– 442 10.1016/j.electacta.2012.10.076CrossRefGoogle Scholar
Todorov, T. K., Tang, J., Bag, S., Gunawan, O., Gokmen, T., Zhu, Y., Mitzi, D.B.. Advanced Energy Materials 3(2012)34–38 10.1002/aenm.201200348CrossRefGoogle Scholar
Barrios-Salgado, E., Nair, M. T. S., Nair, P. K., ECS Journal of Solid State Science and Technology 3 (2014) Q169–Q175 10.1149/2.0131408jssCrossRefGoogle Scholar
García, V. M., Nair, M. T. S., and Nair, P. K., Semicond. Sci. Technol. 14 (1999) 366 10.1088/0268-1242/14/4/015CrossRefGoogle Scholar
García, V. M., Nair, P. K., and Nair, M. T. S., J. Cryst. Growth, 203 (1999) 113 10.1016/S0022-0248(99)00040-8CrossRefGoogle Scholar
Fella, Carolin M., Uhl, Alexander R., Hammond, Ceri, Hermans, Ive, Romanyuk, Yaroslav E., Tiwari, Ayodhya N.. Journal of Alloys and Compounds 567 (2013) 102–106 10.1016/j.jallcom.2013.03.056CrossRefGoogle Scholar
Todorov, T.K., Reuter, K.B., Mitzi, D.B.. Adv. Mater. 22 (2010) E156–E159 10.1002/adma.200904155CrossRefGoogle Scholar
Zhou, Jicheng, You, Liang, Yi, Qiang, Ye, Zhibin. Materials Letters107(2013)225–227 10.1016/j.matlet.2013.05.109CrossRefGoogle Scholar