No CrossRef data available.
Article contents
Crystal Structures and Thermoelectric Properties of Ru1-xRexSiy Chimney-Ladder Compounds
Published online by Cambridge University Press: 26 February 2011
Abstract
The phase relationship of Re-alloyed Ru2Si3 and the variations of the crystal structures and thermoelectric properties of the Ru1-xRexSiy chimney-ladder phases have been studied as a function of the Re concentration. The Ru1-xRexSiy chimney-ladder phases are formed in a wide compositional range. Compositional formula of the chimney-ladder phases are determined to be Ru1-xRexSi1.5386+0.1783x (0.14 ≤ x ≤ 0.76), which are systematically deviated from the idealized composition conforming the valence electron counting rule: VEC=14. Measurements of thermoelectric properties of single crystals with different compositions reveals that the chimney-ladder phases exhibit n-type semiconducting behavior at low Re concentrations and p-type semiconducting behavior at high Re concentrations. These results suggests that the VEC=14 rule can be used for predicting the semiconducting behavior of the chimney-ladder phases through the adjustment of VEC values by substituting elements, producing p-type semiconductors for VEC<14 and n-type for VEC>14, with the carrier concentration related to the deviation from VEC=14.
- Type
- Research Article
- Information
- MRS Online Proceedings Library (OPL) , Volume 980: Symposium II – Advanced Intermetallic-Based Alloys , 2006 , 0980-II05-37
- Copyright
- Copyright © Materials Research Society 2007