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Crystal Chemistry, Synthesis, and Characterization of Infrared Optical Materials

Published online by Cambridge University Press:  21 February 2011

D. O. Kipp ,
C. K. Lowe-Ma  and
T. A. Vanderah
D. O. Kipp
Affiliation:
Chemistry Division (Code 3854), Research Department Naval Weapons Center, China Lake, CA 93555
C. K. Lowe-Ma
Affiliation:
Chemistry Division (Code 3854), Research Department Naval Weapons Center, China Lake, CA 93555
T. A. Vanderah
Affiliation:
Chemistry Division (Code 3854), Research Department Naval Weapons Center, China Lake, CA 93555
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Abstract

Non-oxide inorganic compounds such as sulfides, phosphides, and mixed-anion sulfidephosphides are of interest as possible infrared window materials. Our research on the solid state chemistry and structure-property relationships of these materials includes the directed synthesis of new compounds as well as the study of compounds that have been reported in the literature but which have been incompletely characterized for this application. The present work includes investigations of three ternary sulfide systems: ZnGa2S4, AIn2S4, (A = Ca,Sr,Ba), and CaY2S4. Samples were prepared in polycrystalline form and/or as crystals. New compounds were obtained in our studies of the CaIn2S4, SrIn2S4, and CaY2S4 systems. Compounds were characterized by X-ray diffraction, elemental analysis, FMR, and thermogravimetric analysis.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 152: Symposium H – Optical Materials: Processing and Science , 1989 , 63
Copyright
Copyright © Materials Research Society 1989

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References

REFERENCES

1. Slack, G.A. in Advanced Materials for Optical Windows, G. E. Technical Information Series No. 79CRD071, June 1979.Google Scholar
2. Musikant, S., Tanzilli, R.A., Charles, R.J, Slack, G.A., White, W., and Cannon, R.M. in Advanced Optical Ceramics. Phase 0, G. E. Document No. 78SDR2195, May 1978.Google Scholar
3. Hazen, R.M. and Finger, L.W., in Comparative Crystal Chemistry, (John Wiley & Sons, New York, 1982), p. 136.Google Scholar
4. Muller, O., in Crystal Chemical Data for Ternary Chalcogenide and Pnictide Compounds, Scientific Report No. 1, Air Force Contract No. F19628–71–C–0232, August 1972.Google Scholar
5. Kyle, N.R., Stephens, R.R., Pedinoff, M.E., Sashital, S.R., Gentile, A.L., and Lotspeich, J.F., in Development of New Electro-Optic and Acousto-Optic Materials, Air Force Technical Report RADC–TR–83–243, November 1983.Google Scholar
6. Johnson, C.E., Vanderah, T.A., Bauch, C.G., and Harris, D.C., Proc. SPIE 968, 41 (1988).Google Scholar
7. Hahn, H., Frank, G., Klingler, W., Stoerger, A., and Stoerger, G., Z.anorg. allg. Chem. 279, 241 (1955).Google Scholar
8. Zhang, J.M., Chen, W.W., Dunn, B., and Ardell, A.J., Proc. of the SPIE 968, (1988).Google Scholar
9. A. Wold (private communication), 1988.Google Scholar
10. Nitsche, R., Boelsterli, H.U., and Lichtensteiger, M., J. Phys. Chem. Solids 21, 199 (1961).Google Scholar
11. Beun, J.A., Nitsche, R., and Lichtensteiger, M., Physica 27, 448 (1961).Google Scholar
12. Vengatesan, B., Kanniah, N., and Ramasamy, P., Phys. Stat. Sol. 104, K93 (1987).Google Scholar
13. Hahn, H. and Klingler, W., Z. anorg. allg. Chem. 263, 177 (1950).Google Scholar
14a. Chapuis, G., Niggli, A., and Nitsche, R., Naturwissenschaften 58, 94 (1971). b. G. Chapuis and A. Niggli, J. Solid State Chem. 5, 126 (1972).Google Scholar
15. Donohue, P.C. and Hanlon, J.E., J. Electrochem. Soc. 121, 137 (1974).Google Scholar
16. Eisenmann, B., Jakowski, M., Klee, W., and Schafer, H., Rev. Chim. Miner. 20, 255 (1983).Google Scholar
17. Flahaut, J., Domange, L., and Patrie, M., Bull. Soc. Chim. 1, 105 (1961).Google Scholar
18. Patrie, M. and Flahaut, J., C.R. Acad. Sc. Paris 264, 395 (1967).Google Scholar
19. Tsai, H.L. and Meschter, P.J., J. Electrochem. Soc. 128, 2229 (1981).Google Scholar
20. Park, H.L., Chess, C.A., and White, W.B. in The Rare Earths in Modern Science and Technology, McCarthy, G.J., Rhyne, J.J., and Silber, H.B., Eds.; Plenum Press, N.Y.: 1980; p. 451–6.Google Scholar
21. Gates, Alfred S. Jr., Ph.D. Dissertation, The University of Toledo, 1976.Google Scholar
22. White, W.B. in Advanced Optical Ceramics. Phase II, GE Report for ONR Contract N00014–78–C–0466, DIN:80SDR2172, August 1980.Google Scholar
23. Shannon, R.D., Acta Crystallogr. A32, 751 (1976).Google Scholar