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Conversion of an Aurivillius Phase Bi2SrNaNb3O12 into Its Protonated Form via Treatment with Various Mineral Acids

Published online by Cambridge University Press:  18 March 2011

Masashi Shirata ,
Yu Tsunoda ,
Wataru Sugimoto  and
Yoshiyuki Sugahara
Masashi Shirata
Affiliation:
Department of Applied Chemistry, School of Science and Engineering, Waseda University, Shinjuku-ku, Tokyo 169-8555, JAPAN
Yu Tsunoda
Affiliation:
Department of Applied Chemistry, School of Science and Engineering, Waseda University, Shinjuku-ku, Tokyo 169-8555, JAPAN
Wataru Sugimoto
Affiliation:
Department of Fine Materials Engineering, Faculty of Textile Science and Technology, Shinshu University, Ueda, Nagano, 386-8567, JAPAN
Yoshiyuki Sugahara
Affiliation:
Department of Applied Chemistry, School of Science and Engineering, Waseda University, Shinjuku-ku, Tokyo 169-8555, JAPAN
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Abstract

A protonated form of a layered perovskite was prepared from an Aurivillius phase Bi2SrNaNb3O12via acid treatments, and the effect of the type of mineral acids was investigated. The treatment with HX (X = Cl, Br, I) resulted in the formation of a protonated form H1.8[Sr0.8Bi0.2NaNb3O10], while no reactions were observed for HNO3 and H2SO4 under the present experimental conditions. All the products obtained by HX-treatments exhibited layered structures and the structures of the perovskite-like slabs were preserved.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 658: Symposium GG – Solid-State Chemistry of Inorganic Materials III , 2000 , GG6.24
Copyright
Copyright © Materials Research Society 2001

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References

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