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Controlled Cleavage of Fully-Condensed Silsesquioxane Frameworks: A Revolutionary New Method for Manufacturing Precursors to Hybrid Inorganic/Organic Materials
Published online by Cambridge University Press: 10 February 2011
Abstract
The reaction of readily available Cy8Si8O12 (3) with triflic acid (TfOH) can produce two different ditriflates derived from controlled cleavage of Si-O-Si linkages. These ditriflates can be subsequently hydrolyzed to four different incompletely condensed silsesquioxanes, which are attractive precursors to hybrid inorganic/organic materials.
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- Copyright © Materials Research Society 1999
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