Hostname: page-component-586b7cd67f-2brh9 Total loading time: 0 Render date: 2024-11-25T17:48:43.540Z Has data issue: false hasContentIssue false
  • English
  • Français

Control Of Polyimide Surface Property By Changing The Surface Morphology

Published online by Cambridge University Press:  15 February 2011

Kang-Wook Lee
Kang-Wook Lee*
Affiliation:
IBM, T. J. Watson Research Center, P.O. Box 218, Yorktown Heights, NY 10598
Get access

Abstract

The surface properties of polyimide can be changed without altering the bulk properties. The surface layer (around 200 Å) of fully cured PMDA-ODA polyimide is chemically modified to polyamic acid which is subsequently imidized at 230 °C for 30 min to give an unordered polyimide surface. This unordered layer seems amorphous since it swells well in NMP. The modified surfaces are analyzed by surface sensitive techniques such as contact angle measurement, XPS, ISS, and external reflectance infrared (ERIR) spectroscopy. Adhesion of polyimides and chromium on the amorphous polyimides is greatly enhanced. Interdiffusion and subsequent mechanical interlocking are the major contributions to the polyimide-polyimide adhesion.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 227: Symposium J – Materials Science of High Temperature Polymers for Microelectronics , 1991 , 347
Copyright
Copyright © Materials Research Society 1991

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Bessonov, M.I., Koton, M.M., Kudryavtsev, V.V., Laius, L.A., Polyimides: Thermally Stable Polymers, (Consultants Bureau: NY, 1987).Google Scholar
2. Mandelkern, L. in Physical Properties of Polyimides, edited by Mark, J.E., Eisenberg, A., Grasessley, W.W., Mandelkern, L. and Koenig, J.L., (ACS: Washington, DC, 1984).Google Scholar
3. Pliskin, W.A., Chapple-Sokol, J.D. and Lee, K.-W., unpublished work.Google Scholar
4. Takahashi, N., Yoon, D.Y. and Parrish, W., Macromolecules, 17, 2583 (1984).Google Scholar
5. Lee, K.-W., Kowalczyk, S.P., Shaw, J.M., Macromolecules, 23, 2097 (1990).Google Scholar
6. Lee, K.-W. and Kowalczyk, S.P., in Metallization of Polymers, edited by Sacher, E., Pireaux, J-J., and Kowalczyk, S.P. (ACS Sym. Series, vol 440; ACS: Washington, DC, 1990) chapter 13.Google Scholar
7. Ree, M. and Lee, K.-W., further work to provide a direct evidence on the ordering of the modified polyimide surface is in progress.Google Scholar