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Continuous High Temperature Lubrication of Ceramics by Carbon Generated Catalytically

Published online by Cambridge University Press:  28 February 2011

James L. Lauer
Affiliation:
Department of Mechanical Engineering, Aeronautical Engineering, and Mechanics, Rensselaer Polytechnic Institute, Troy, New York 12180-3590
Scott R. Dwyer
Affiliation:
Department of Mechanical Engineering, Aeronautical Engineering, and Mechanics, Rensselaer Polytechnic Institute, Troy, New York 12180-3590
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Abstract

A system for the continuous lubrication of ceramic surfaces at high temperatures by a carbon formed exclusively at the wear surfaces is described. Thelubricant is delivered as a simple gas, ethylene, which is catalytically transformed. No reaction products are left which contain bearing surface material and the only non-volatile product is lubricating carbon. One of the wearing surfaces must contain or have an overlay of nickel (about 1000 A thick in this work) and, preferably, a coating of nickel oxide on top to reducenickel wear during startup. Since the carbon is formed only on nickel and the oxide is worn only in the weartrack, only the wear track is lubricated. The laboratory system consisted of a sapphire pin on a nickel-coated rotating alumina disc. Ethylene was delivered only to the conjunction region, which was surrounded by air. Contact pressures were about 200 MPa, linear speeds between 3 and 9cm/sec. Friction coefficients dropped from 0.6 to 0.06 when ethylene was delivered to the contact at 500°C. Wear rateswere not measureable under operating conditions. Cases other than ethylene and catalysts other than nickel will be explored in further work.

Type
Research Article
Copyright
Copyright © Materials Research Society 1989

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References

1. (a) Graham, E.E., and Klaus, E.E., “Lubrication from the Vapor Phase at High Temperatures,” ASLE Transactions, 29(2), 229234 (1986). (b) Klaus, E.E., Phillips, J., Lin, S.C., Wu, N.L. and Duda, L., ”Structure of Films Formed During the Deposition of Lubrication Molecules on Iron and Silicon Carbide,” STLE Paper NO. 88-TC-5A-2, Technical Reprints of the Society of Tribologists and Lubrication Engineers, ASME/STLE Tribology Conference, Baltimore, October 1988.CrossRefGoogle Scholar
2. McCarthy, J.G., Hou, P.Y., Sheridan, D., and Wise, H., “Reactivity of Surface Carbon on Nickel Catalysts: Temperature-Programmed Surface Reaction with Hydrogen and Water,” in Coke Formation on Metal Surfaces (Albright, L.F. and Baker, R.T.K., eds.), ACS Symposium Series NO. 202, 253282 (1982).CrossRefGoogle Scholar
3. Lauer, J.L., “Continuous Shock Wave Reactor for Chemicals Production and Reaction Studies,” Chem. Engineering Science, 22, 209–15 (1967).CrossRefGoogle Scholar
4. LaCava, A.I., Fernandez-Raone, E.D., Isaacs, L.L., and Caraballo, M., ”Effect of Hydrogen on the Iron- and Nickel-Catalyzed Formation of Carbon from Benzene, in Coke Formation on Metal Surfaces (Albright, L.F. and Baker, R.T.K., eds.), ACS Symp. Ser. 202, 253282 (1982).Google Scholar
5. Mori, S., and Imaizumi, Y., “Absorption of Model Compounds of Lubricant on Nascent Surfaces of Mild and Stainless Steels under Dynamic Conditions,” 31(4), 449453 (1988).Google Scholar
6. Lauer, J.L. and Bunting, B.G., “Catalytic Generation of Lubricants from Carbonaceous Gases on Surfaces Undergoing Friction at High Temperatures.” Paper No. 880019 in Recent Developments in the Adiabatic Engine, SAE Publication SP-738, p. 5160 (February 1988). Available from Society of Automotive Engineers, Inc., 400 Commonwealth Drive, Warrendale, PA 15096-0001.Google Scholar
7. Nakamizo, M., and Tamai, K., “Raman Spectra of the Oxidized and Polished Surfaces of Carbon,” Carbon, 22, 197 (1984).CrossRefGoogle Scholar
8. Kinoshita, K., Carbon, Electrochemical and Physicochemical Properties, John Wiley & Sons, NY (1988).Google Scholar