Hostname: page-component-78c5997874-dh8gc Total loading time: 0 Render date: 2024-11-16T17:02:17.804Z Has data issue: false hasContentIssue false
  • English
  • Français

Comprehensive Structural Study of Pre- and Post-Heat Treated Compression Molded Polyurethane Samples of Varying Composition Studied by Scanning Probe Techniques

Published online by Cambridge University Press:  21 March 2011

M.E. Hawley ,
E.B. Orler ,
D.A. Wrobleski ,
R.P. Hjelm  and
G.W. Brown
M.E. Hawley
Affiliation:
Materials Science and Technology Division, Los Alamos National Laboratory, Los Alamos, NM 87545
E.B. Orler
Affiliation:
Materials Science and Technology Division, Los Alamos National Laboratory, Los Alamos, NM 87545
D.A. Wrobleski
Affiliation:
Materials Science and Technology Division, Los Alamos National Laboratory, Los Alamos, NM 87545
R.P. Hjelm
Affiliation:
LANSCE, Los Alamos National Laboratory, Los Alamos, NM 87545
G.W. Brown
Affiliation:
Materials Science and Technology Division, Los Alamos National Laboratory, Los Alamos, NM 87545
Get access

Abstract

Only a limited number of structural studies have been performed on polyurethanes using scanning probe techniques to determine both the microstructure and the corresponding distribution of hard and soft segments within samples. This type of information is needed to better understand the mechanical properties of these materials and to facilitate modeling. In order to address these issues, we have fabricated a series of compression molded segmented poly(ester urethane) samples with hard (HS) to soft segment ratios from 19 to 100%. Samples were examined using scanning probe phase imaging techniques to obtain the topography and corresponding distribution of hard domains before and after heating at 100°C.

A number of significant differences were observed between the pre- and post-heat treated samples. Variations in structure and heat-induced morphological changes were directly related to HS content. Fine strand- or fibril-like structures were most prominent in the 23 and 19% HS sample but first appeared at 30% HS. Harder, thicker elongated structures dominated the surface of the100% HS sample and were seen to a limited extent on all samples, especially after annealing and quenching. The 23% HS sample surface structure depended on quenching rate and time after treatment.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 661: Symposium KK – Filled & Nanocomposite Polymer Materials , 2000 , KK4.7
Copyright
Copyright © Materials Research Society 2001

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Miller, J.A.; Lin, S.B.; Hwang, K.K.S.; Wu, K.S.; Gibson, P.E.; Cooper, S. L. Macromolecules, 18, 32 (1985).Google Scholar
2. Leung, L.M., and Koverstein, J.T., J. Polym. Sci. Polym. Phys. Ed., 23, 1883–1913 (1985).Google Scholar
3. Miller, J.A., Cooper, S.L., Han, C.C., and Pruckmayr, G., Macromolecules, 17, 1066 (1984).Google Scholar
4. Koberstein, J.T.; Galambos, A.F.; Leung, L.M. Macromolecules, 25, 6195 (1992).Google Scholar
5. Wilkes, G.L.; Emerson, J.A. J. Appl. Phys., 47, 4261 (1976).Google Scholar
6. , Karbach and Drechsler, D., Surf. Interface Anal. 27, 401 (1999).Google Scholar
7. McLean, R.S. and Sauer, B.B., Macromolecules, 30, 8314 (1997).Google Scholar
8. Garrett, J.T., Runt, J., and Lin, J.S., Macromolecules, 33, 6353 (2000).Google Scholar
9. Manual Dimension 3000, Digital Instruments, division of Veecho, Santa Barbara, CA. Google Scholar