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Coating of Ultrathin Polymer Films on Carbon Nanotubes by a Plasma Treatment

Published online by Cambridge University Press:  11 February 2011

Peng He
Affiliation:
Dept. of Chemical and Materials Engineering, Engineering, University of Cincinnati, Cincinnati, OH 45221
Jie Lian
Affiliation:
Dept. of Nuclear Engineering and Radiological Science, University of Michigan, Ann Arbor, MI 48109
Donglu Shi
Affiliation:
Dept. of Chemical and Materials Engineering, Engineering, University of Cincinnati, Cincinnati, OH 45221
Lumin Wang
Affiliation:
Dept. of Nuclear Engineering and Radiological Science, University of Michigan, Ann Arbor, MI 48109
David Mast
Affiliation:
Dept. of Physics,, Engineering, University of Cincinnati, Cincinnati, OH 45221
Wim J. van Ooij
Affiliation:
Dept. of Chemical and Materials Engineering, Engineering, University of Cincinnati, Cincinnati, OH 45221
Mark Schulz
Affiliation:
Dept. of Mechanical, Engineering, University of Cincinnati, Cincinnati, OH 45221
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Abstract

Ultrathin polymer films have been deposited on both single- and multi-wall carbon nanotubes using a plasma polymerization treatment. HRTEM experiments showed that an extremely thin film of the pyrrole layer (2–7 nm) was uniformly deposited on the surfaces of the nanotubes including inner wall surfaces of the multi-wall nanotubes. Time-of-Flight Secondary ion mass spectroscopy (TOFSIMS) experiments confirmed the nanosurface deposition of polymer thin films on the nanotubes. The deposition mechanisms and the effects of plasma treatment parameters are discussed.

Type
Research Article
Copyright
Copyright © Materials Research Society 2003

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References

REFERENCES

1. Siegel, R. W., Nanostructured Materials. 3, 1 (1993).Google Scholar
2. Hadjipanayis, G. C. and Siegel, R. W., Nanophase materials, Synthesis-properties-applications (Kluwer Press, Dordrecht, 1994).Google Scholar
3. Whitesides, G. M., Mathias, J. P., and Seto, C. T., Science, 254, 1312 (1991).Google Scholar
4. Stucky, C. D., and MacDougall, J. E., Science, 247, 669 (1990).Google Scholar
5. Gleiter, H., Nanostructured Materials, 6, 3 (1995).Google Scholar
6. Nanotechnology, Wolde, A. T., ED. (STT Netherlands Study Center for Technology Trends, The Hague, The Netherlands, 1998).Google Scholar
7. Timp, G., “Nanotechnology,” AIP Press, Springer, 1998.Google Scholar
8. Bar-Cohen, Y., “Electroactive Polymers as Artificial Muscles - Reality and Challenges”, 42nd AIAA Structures, Dynamics, and Materials Conference (SDM), Gossamer Spacecraft Forum (GSF), Seattle WA, 2001) 110.Google Scholar
9. Mazzoldi, D. D. and Baughman, R. H., “Electro-mechanical behavior of carbon nanotube sheets in electrochemical actuators”, Electroactive Polymer Actuators and Devices (SPIE Proceedings, 2000) 2532.Google Scholar
10. Fraysse, J., Minett, A. I., Gu, G., Roth, S., et al., “Towards the demonstration of actuator properties of a single carbon nanotube,” Current Applied Physics, 1, 407411 (2001).Google Scholar
11. Lebedev, N. G., Zaporotskova, I. V., and Chernozatonskii, L. A., “On the Estimation of Piezoelectric Modules of Carbon and Boron Nitride Nanotubes,” 2001, Volograd State University, 400062 Volgograd, Russia, and Institute of Biochemical Physics of RAS, 117334, Moscow, Russia Google Scholar
12. Shi, D. and Ooij, W. J. v., “Uniform Deposition of Ultrathin Polymer Films on the Surface of Aluminum Nanoparticles by a Plasma Treatment,” Appl. Phys. Lett., 78, 1243 (2001).Google Scholar
13. Inagaki, N., Tasaka, S., and Ishii, K., J. App. Poly. Sci., 48, 1433 (1993).Google Scholar
14. Bayer, C., Karches, M., Mattews, A. and Von Rohr, P. R., Chem. Eng. Technol. 21, 427 (1998)Google Scholar
15. Eufinger, S., van Ooij, W. J., and Ridgway, T. H., Journal of Appl. Pol. Sci., 61, 1503 (1996).Google Scholar
16. van Ooij, W. J., Eufinger, S., and Ridgway, T. H., Plasma and Polymers, 1, 231 (1996).Google Scholar
17. Applied Sciences, Inc., 141 W. Xena Ave., P.O. Box 579, Cedarville, OH 45314–0579Google Scholar