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Cleavable Thermosetting Epoxies: a Tool for Monitoring Cure Chemistry Perturbation at an Interface

Published online by Cambridge University Press:  15 February 2011

Michael D. Gilbert
Michael D. Gilbert*
Affiliation:
Army Research Laboratory, AMSRL-MA-PB, Watertown, MA 02172-0001
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Abstract

A diepoxide containing a disulfide linkage, capable of being reductively cleaved was synthesized. This compound was cured with standard amine curing agents to form intractable network polymers, which were then decomposed into soluble fragments, allowing the effects of network formation on cure chemistry to be evaluated. This system was then used to investigate the effects of an alumina interface on epoxy network formation.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 304: Symposium H – Polymer/Inorganic Interfaces , 1993 , 49
Copyright
Copyright © Materials Research Society 1993

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References

1. Isaacs, N.S. and Parker, R.E., J. Chem. Soc.. 1960, 3497.Google Scholar
2. Harrison, D.J.P., Yates, W.R., Johnson, J. F., JMS-Rev. Macromol. Chem. Phys. C25(4), 481 (1985).Google Scholar
3. Tesoro, G.C. and Sastri, V., J. Appl. Polym. Sci. 39, 1425 (1990). V.R. Sastri and G.C. Tesoro, 1. Appl. Polym. Sci. 39, 1439 (1990).Google Scholar
4. Zukas, W.X., Craven, K.J. and Wentworth, S.E., J. Adhesion 33, 89 (1990).Google Scholar