Hostname: page-component-78c5997874-4rdpn Total loading time: 0 Render date: 2024-11-19T04:34:00.897Z Has data issue: false hasContentIssue false
  • English
  • Français

Chemical Reactivity of Metal Particles Produced by Laser Ablation into Liquids

Published online by Cambridge University Press:  16 February 2011

W. L. Parker  and
Philip Boudjouk
W. L. Parker
Affiliation:
Department of Chemistry, North Dakota State University, Fargo, ND 58105
Philip Boudjouk
Affiliation:
Department of Chemistry, North Dakota State University, Fargo, ND 58105
Get access

Abstract

Spectroscopic evidence of the chemical differences between metal particles produced by laser ablation of metals into reactive fluid solvents and metal particles produced by less energetic means is presented. Specifically. 1) ablation of copper into fluid methanol produces metal particles in which some fraction of the metal is present In the cuprous oxidation state and 2) ablation of nickel into tetrahydrofuran results In metal particles less reactive to the solvent than those produced by ultrasound promoted chemical reduction.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 191: Symposium N – Laser Ablation for Materials Synthesis , 1990 , 103
Copyright
Copyright © Materials Research Society 1990

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

[1] Koerner von Gustorf, E.A., Jaenicke, O., Wolfbeis, O. and Eady, C.R., Angewandte Chemie, Int'l Edition 14, 278 (1975)Google Scholar
[2] Cooper, W.F. and Parker, W.L., Computers and Chemistry accepted for publicationGoogle Scholar
[3] Curtis, Andrew C., Duff, Daniel G., Edwards, Peter P., Jefferson, David A., Johnson, Brian F. C., Kirkland, Angus I., Wallace, Andrew S., J. Phys. Chem. 92, 2270–2275, (1988)Google Scholar
[4] Sledle, A.R., Velapoldi, R.A., and Erickson, N., Appl. Surf. Scd. 3, 229–235 (1979)Google Scholar
[5] Nakamoto, K., Infrared and Raman Spectra of Inorganic and Coordination Compounds Third Edition, Wiley Interscience, New York (1978)Google Scholar
[6] Fleisch, T.H. and Mleville, R.L., J. Catalysis 90, 165–172 (1984)Google Scholar
[7] Ryberg, R., Phys. Rev. Lett. 49, 1579–1586 (1982)Google Scholar
[8] Boudjouk, P. R., Rajkumar, A.B. and Parker, W.L., submitted to Organometal 1 icsGoogle Scholar
[9] Jacobsen, J.R., Thesis, M.S., North Dakota State University, 1989 Google Scholar
[10] Parker, W.L., Boudjouk, P., and Rajkumar, A.B., J. Am. Chem. Soc. accepted for publicationGoogle Scholar