Hostname: page-component-cd9895bd7-p9bg8 Total loading time: 0 Render date: 2024-12-27T02:30:25.193Z Has data issue: false hasContentIssue false
  • English
  • Français

Characterization of the Polymer-Filler Interface in γ-Irradiated Silica-Reinforced Polysiloxane Composites

Published online by Cambridge University Press:  01 February 2011

Allen T. Chien ,
Bryan Balazs  and
James LeMay
Allen T. Chien
Affiliation:
Chemistry and Materials Science Directorate, Lawrence Livermore National Laboratory, Livermore, CA 94551
Bryan Balazs
Affiliation:
Chemistry and Materials Science Directorate, Lawrence Livermore National Laboratory, Livermore, CA 94551
James LeMay
Affiliation:
Chemistry and Materials Science Directorate, Lawrence Livermore National Laboratory, Livermore, CA 94551
Get access

Abstract

The changes in hydrogen bonding at the interface of silica-reinforced polysiloxane composites due to aging in gamma radiation environments were examined in this study. Solvent swelling was utilized to determine the individual contributions of the matrix polymer and polymer-filler interactions to the overall crosslink density. The results show how the polymer-filler hydrogen bonding dominates the overall crosslink density of the material. Air irradiated samples displayed decreased hydrogen bonding at the polymer-filler interface, while vacuum irradiation revealed the opposite effect.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 629: Symposium FF – Interfaces, Adhesion and Processing in Polymer Systems , 2000 , FF5.14
Copyright
Copyright © Materials Research Society 2000

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1 Kraus, G., Rubber Chem. Tech., 38, 1070 (1965).Google Scholar
2 Vondracek, P. and Pouchelon, A., Rubber Chem. Technol., 63, 202 (1990).Google Scholar
3 Cochrane, H. and Lin, C., Rubber Chem. Technol., 66, 48 (1993).Google Scholar
4 Polmanteer, K. and Lentz, C., Rubber Chem. Technol., 48, 795 (1975).Google Scholar
5 Flory, P. J., Principles of Polymer Chemistry, Cornell University Press, Ithaca, New York (1953).Google Scholar
6 French, D., J. Appl. Poly. Sci., 25, 665 (1980).Google Scholar
7 O'Donnell, J. and Sangster, D., Principles of Radiation Chemistry, Edward Arnold Publishers Ltd., London (1970).Google Scholar
8 Tegieve, M. and Kiselev, V., Z. Fiz. Khim., 35, 1381 (1961).Google Scholar
9 Wagner, M., Rubber Chem. Technol., 49, 703 (1976).Google Scholar
10 Primak, W. and Kampwirth, R., J. Appl. Phys., 39, 5651 (1968).Google Scholar