Hostname: page-component-586b7cd67f-t7fkt Total loading time: 0 Render date: 2024-11-25T15:51:51.179Z Has data issue: false hasContentIssue false
  • English
  • Français

Characterization of Medium-range Order in Self-Assembled Organic-inorganic Hybrid by Fluctuation X-ray Microscopy

Published online by Cambridge University Press:  01 February 2011

Lixin Fan ,
David Paterson ,
Ian McNulty ,
M. M. J. Treacy ,
Dushyant Kumar ,
Phong Du ,
Ulrich Wiesner  and
J. Murray Gibson
Lixin Fan
Affiliation:
[email protected], Argonne National Lab, Advanced Photon Source, 9700 S. Cass Ave., Argonne, IL, 60439, United States
David Paterson
Affiliation:
[email protected], Argonne National Lab, Advanced Photon Source, 9700 S. Cass Ave., Argonne, IL, 60439, United States
Ian McNulty
Affiliation:
[email protected], Argonne National Lab, Advanced Photon Source, 9700 S. Cass Ave., Argonne, IL, 60439, United States
M. M. J. Treacy
Affiliation:
[email protected], Arizona State University, Department of Physics and Astronomy, Tempe, AZ, 85287, United States
Dushyant Kumar
Affiliation:
[email protected], Arizona State University, Department of Physics and Astronomy, Tempe, AZ, 85287, United States
Phong Du
Affiliation:
[email protected], Cornell University, Materials Science & Engineering,, Ithaca, NY, 14853, United States
Ulrich Wiesner
Affiliation:
[email protected], Cornell University, Materials Science & Engineering,, Ithaca, NY, 14853, United States
J. Murray Gibson
Affiliation:
[email protected], Argonne National Lab, Advanced Photon Source, 9700 S. Cass Ave., Argonne, IL, 60439, United States
Get access

Abstract

The control of formation and ordering of self assembled nanostructures, with medium- to long-range order, is a challenge that limits advances in many fields of nanotechnology. We have developed a technique, which we call fluctuation x-ray microscopy, that offers quantitative insight into medium-range correlations in disordered materials at nanometer- and larger-length scales. We examined the influence of sol-gel process variables on medium range order in PI-b-PEO/ aluminosilicate bulk using this technique. The nano-structuring of inorganic materials was directed by polymer self-assembly. The medium range correlation between the nanostructures in two hybrids was quantitatively examined and compared.

Keywords

self-assemblynanostructuredefects
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 960: Symposium N – Self Assembly of Nanostructures Aided by Ion- or Photon-Beam Irradiation—Fundamentals and Applications , 2006 , 0960-N09-09
Copyright
Copyright © Materials Research Society 2007

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Huo, Q., et al., Science, 268, 1324 (1995).Google Scholar
2. Firouzi, A., et al., Science, 267, 1138 (1995).Google Scholar
3. Huo, Q., Margolese, D. and Stucky, G. D., Chem. Mater, 8, 1147 (1996).Google Scholar
4. Bagshaw, S. A., Prouzet, E. and Pinnavaia, T. J., Science, 269, 1242 (1995).Google Scholar
5. Attard, G. S., Glyde, J. C. and Göltner, C. G., Nature, 378, 366 (1995).Google Scholar
6. Firouzi, A.; et al., J. Am. Chem. Soc., 119, 3596 (1997).Google Scholar
7. Templin, M. et al., Science, 278, 1795–1798 (1997).Google Scholar
8. Simon, P. F. W., et al., Chem. Mater., 13, 3464 (2001).Google Scholar
9. Fan, L., et al., Nucl. Inst. and Meth. B, 238, 196 (2005).Google Scholar
10. Fan, L., et al., Mater. Res. Soc. Symp. Proc. 840, Q6.7.1 (2005).Google Scholar
11. Treacy, M. M. J., et al.,. Rep. Prog. Phys. 68, 2899 (2005).Google Scholar
12. Fan, L., et al., J. of Microscopy (2007) in print.Google Scholar
13. Treacy, M. M. J., Voyles, P. M., and Gibson, J. M., J. Non-Cryst. Solids, 266–269, 150 (2000).Google Scholar
14. Gibson, J. M., et al., Ultramicroscopy, 83, 169 (2000).Google Scholar
15. Allgaier, J., et al., Macromolecules, 30, 1582 (1997).Google Scholar
16. Hillmyer, M. A. and Bates, F. S., Macromolecules, 29, 6994 (1996.)Google Scholar
17. Schmidt, S. C. and Hillmyer, M. A., J. Polym. Sci. Pt. B-Polym. Phys. 40, 2354 (2002).Google Scholar
18. Du, P., et al., Adv. Mater. 16, 953 (2004).Google Scholar