Hostname: page-component-78c5997874-8bhkd Total loading time: 0 Render date: 2024-11-18T12:20:20.106Z Has data issue: false hasContentIssue false

Characterization of Gap Defect States in Hydrogenated Amorphous Silicon Materials

Published online by Cambridge University Press:  01 February 2011

Lihong Jiao
Affiliation:
[email protected], Grand Valley State University, School of Engineering, 301 W. Fulton St, Grand Rapids, MI, 49504, United States, (616)3316844
C. R. Wronski
Affiliation:
[email protected], Pennsylvania State University, Electrical Engineering, University Park, PA, 16802, United States
Get access

Abstract

An enhanced simulation model based on the carrier recombination through these states was developed to characterize the gap defect states in hydrogenated amorphous silicon materials (a-Si:H). The energy dependent density of electron occupied gap states, kN(E), was derived directly from Dual Beam Photoconductivity (DBP) measurements at different bias currents. Through Gaussian de-convolution of kN(E), the energy peaks of the multiple defect states, including both neutral and charged states, were obtained. These energy levels, together with the information on the capture cross sections, were used as known input parameters to self-consistently fit the subgap absorption spectra, the electron mobility-lifetime products over a wide range of generation rates, as well as the energy dependent density of electron occupied gap state spectra. Accurate gap state information was obtained and the nature of the defect states was studied. Simulation results on light degraded hydrogen diluted, protocrystalline a-Si:H show that the density of charged states is 2.3 times that of neutral states. The two states close to the midgap act as effective recombination centers at low generation rates and play key roles in photoconductivity studies.

Type
Research Article
Copyright
Copyright © Materials Research Society 2008

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Pickin, W. Alonso, J.C. and Mendoza, D. J. Phys. C, vol. 20, p341, (1987)Google Scholar
2. Yasa, Z.A. Jackson, W.B. and Amer, N.M. Appl. Opt., vol. 21, p21 (1982)Google Scholar
3. Jiao, L. Liu, H. Semoushikiana, S. Lee, Y. and Wronski, C.R. 9th International Photovoltaic Science and Engineering Conf., p641, (1996)Google Scholar
4. Pearce, J. M. Deng, J. Vlahos, V. Collins, R. W. Wronski, C. R. 3rd World Conference on Photovoltaic Energy Conversion, 2, p1588 (2003)Google Scholar
5. Lee, Y. Jiao, L. Liu, H. Lu, Z. Collins, R.W. and Wronski, C. R. Conf. Record of 25th IEEE PVSEC (IEEE, 1996), 1165 (1996)Google Scholar
6. Kalma, A.H. et al. , Ed. Vook, F. L. (Plenum Press, New York–London) p153, (1968)Google Scholar
7. Matsui, K. and Baruch, P. University of Tokyo Press, Toyko, p282, (1968)Google Scholar
8. Simmons, J.G. and Taylor, G.W. Phys. Rev. B, 4, p502 (1971)Google Scholar
9. Rose, A. Phys. Rev. 97, p322 (1955)Google Scholar
10. Deng, J. Ross, B, Albert, M. Collins, R. W. and Wronski, C. R. Mater. Res. Soc. Symp. Proc., 0910-A02-02, (2006)Google Scholar