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Ceramic formulation and processing design for plutonium disposition

Published online by Cambridge University Press:  15 February 2011

Neil C. Hyatt
Affiliation:
Immobilization Science Laboratory, Department of Engineering Materials, University of Sheffield, Sir Robert Hadfield Building, Mappin Street, Sheffield, S1 3JD, UK
Martin Stennett
Affiliation:
Immobilization Science Laboratory, Department of Engineering Materials, University of Sheffield, Sir Robert Hadfield Building, Mappin Street, Sheffield, S1 3JD, UK
Andreas Jenni
Affiliation:
Immobilization Science Laboratory, Department of Engineering Materials, University of Sheffield, Sir Robert Hadfield Building, Mappin Street, Sheffield, S1 3JD, UK
Daniel Reid
Affiliation:
Immobilization Science Laboratory, Department of Engineering Materials, University of Sheffield, Sir Robert Hadfield Building, Mappin Street, Sheffield, S1 3JD, UK
and Ewan R. Maddrell
Affiliation:
National Nuclear Laboratory, Sellafield, Seascale, Cumbria, CA20 1PG, UK
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Abstract

The focus of this research programme is to develop a single phase ceramic wasteform for waste PuO2 that is unsuitable for fuel manufacture. A suite of synthetic mineral systems have been considered including titanate, zirconate, phosphate and silicate based matrices. Although a wealth of information on plutonium disposition in some of the systems exists in the literature, the data is not always directly comparable which hinders comparison between different ceramic hosts. The crux of this research has been to compile a database of information on the proposed hosts to allow impartial comparison of the relative merits of each system.

Type
Research Article
Copyright
Copyright © Materials Research Society 2009

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