Hostname: page-component-cd9895bd7-gbm5v Total loading time: 0 Render date: 2024-12-27T02:42:08.207Z Has data issue: false hasContentIssue false
  • English
  • Français

Cellulose Conversion to Sugar Alcohol by Solution Plasma Processing

Published online by Cambridge University Press:  16 September 2015

Anyarat Watthanaphanit ,
Hoonseung Lee  and
Nagahiro Saito
Anyarat Watthanaphanit*
Affiliation:
Social Innovation Design Center (SIDC), Institute of Innovation for Future Society, Nagoya University, Nagoya 464-8603, Japan Department of Materials, Physics and Energy Engineering, Graduate School of Engineering, Nagoya University, Nagoya 464-8603, Japan
Hoonseung Lee
Affiliation:
Department of Materials, Physics and Energy Engineering, Graduate School of Engineering, Nagoya University, Nagoya 464-8603, Japan
Nagahiro Saito
Affiliation:
Social Innovation Design Center (SIDC), Institute of Innovation for Future Society, Nagoya University, Nagoya 464-8603, Japan Department of Materials, Physics and Energy Engineering, Graduate School of Engineering, Nagoya University, Nagoya 464-8603, Japan Green Mobility Collaborative Research Center, Nagoya University, Nagoya 464-8603, Japan
*
*Email to: [email protected]
Get access

Abstract

Cellulose was selectively converted to sugar alcohols (sorbitol and mannitol) over a supported-metal catalyst ruthenium on carbon (Ru/C) by the application of plasma in cellulose aqueous suspension. Generally, conversion of cellulose to sugar alcohol should be done under H2 pressure and high temperature. The goal of using solution plasma process (SPP) in this study is to initiate “self-hydrogenation” by reactive hydrogen species generated from the plasma due to dissociation of water medium. The sugar alcohols were produced at room temperature and atmospheric pressure. Electrospray ionization mass spectrometric analysis indicates that the SPP is a potent tool to promote the conversion of cellulose to sugar alcohols.

Keywords

biomaterialenvironmentally benignSustainability
Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1745: Symposium FF – Materials as Tools for Sustainability , 2015 , mrsf14-1745-ff13-07.r1
Copyright
Copyright © Materials Research Society 2015 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Song, J., Fan, H., Ma, J., and Han, B., Green Chem. 15, 2619–2635 (2013).CrossRefGoogle Scholar
Kobayashi, H., Komanoya, T., Guha, S. K., Hara, K., and Fukuoka, A.. Appl. Catal. A-Gen. 409–410, 13–20 (2011).CrossRefGoogle Scholar
Watthanaphanit, A. and Saito, N., Polym. Degrad. Stabil. 98, 1072–1080 (2013).CrossRefGoogle Scholar
Prasertsung, I., Damrongsakkul, S., Terashima, C., Saito, N., and Takai, O., Carbohyd. Polym. 87, 2745–2749 (2012).CrossRefGoogle Scholar
Deng, W., Tan, X., Fang, W., Zhang, Q., and Wang, Y.. Catal. Lett. 133, 167–174 (2009).CrossRefGoogle Scholar