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Catalytic Decomposition of N2O ON ZrO2 and Co/Ni/ZrO2 Systems

Published online by Cambridge University Press:  15 February 2011

H. C. Zeng ,
J. Lin ,
W. K. Teo ,
J. Wu  and
K. L. Tan
H. C. Zeng
Affiliation:
Department of Chemical Engineering, Faculty of Engineering, National University of Singapore, 10 Kent Ridge Crescent, Singapore 0511
J. Lin
Affiliation:
Department of Physics, Faculty of Science, National University of Singapore, 10 Kent Ridge Crescent, Singapore 0511
W. K. Teo
Affiliation:
Department of Chemical Engineering, Faculty of Engineering, National University of Singapore, 10 Kent Ridge Crescent, Singapore 0511
J. Wu
Affiliation:
Department of Chemical Engineering, Faculty of Engineering, National University of Singapore, 10 Kent Ridge Crescent, Singapore 0511
K. L. Tan
Affiliation:
Department of Physics, Faculty of Science, National University of Singapore, 10 Kent Ridge Crescent, Singapore 0511
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Abstract

Monoclinic ZrO2 and its supported catalysts Co/Ni/ZrO2 for catalytic decomposition of N2O have been studied with FTIR, EDAX, XPS, and the evaluation of activity of the catalysts. It is found that monoclinic ZrO2 alone has the catalytic effect for N2O decomposition although the gas decomposes on Co/Ni/ZrO2 more efficiently. The XPS study shows that only Co exists in the surface region of ZrO2. In evaluation experiments, it is found that when Co/Ni exceeds a threshold concentration, the conversion of N2O is no longer accelerated with the increase of Co/Ni content. The gas decomposition on Co/Ni/ZrO2 can be described as first order with respect to partial pressure of N2O. No nitrogen N(ls) photoelectrons were detected for the catalysts after N2O decomposition. Surface reactions on ZrO2 and Co/Ni/ZrO2, including the behaviour of retained carbon (Cls) and N2O decomposition mechanism, will also be addressed.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 344: Symposium I – Materials and Processes for Environmental Protection , 1994 , 21
Copyright
Copyright © Materials Research Society 1994

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References

[1] Thiemans, M.H. and Trogler, W.C., Science 251 (1991) 932.Google Scholar
[2] Li, Y. and Armor, J.N., Applied Catalysis B 1 (1992) L21.Google Scholar
[3] Pomonis, P., Vatts, D., Lycourghiotis, A. and Kordulis, C., J. Chem. Soc, Faraday Trans. 1, 81 (1985) 2043.Google Scholar
[4] Kobayashi, H. and Hara, K., in: Bell, A.T. and Hegedus, L.L.. (Editors), Catalysis Under Transient Conditions, ACS. Sym. Ser., 1982 p. 163.Google Scholar
[5] Aparicio, L.M., Ulla, M.A., Millman, W.S. and Dumesic, J.A., J. Catal. 110 (1988) 330.Google Scholar
[6] Slinkin, A.A., Lavrovskaya, T.K., Mishin, I.V. and Rubinshtein, A.M., Kinet. Katal. 19 (1978) 992.Google Scholar
[7] Leglise, J., Petunchi, J.O. and Hall, W.K., J. Catal. 121 (1990) 422.Google Scholar
[8] Panov, G.I., Sobolev, V.I. and Kharitonov, S., J. Mol. Catal. 61 (1990) 85.Google Scholar
[9] Li, Y. and Armor, J.N., US Patent Appl. (1990).Google Scholar
[10] Klein, R. and Siegel, R., Surface Sci. 92 (1980) 337.Google Scholar
[11] Raj, S. L., Viswanathan, B. and Srinivasan, V., Indian J. of Chem. 21A (1982) 689.Google Scholar
[12] Giamello, K., Volante, M., Fubini, B., Geobaldo, F. and Morterra, C., Mater. Chem. Phys. 29 (1991) 279.Google Scholar
[13] Mercera, P.D.L., van Ommen, J.G., Doesburg, E.B.M., Burggraaf, A.J. and Ross, J.R.H., Applied Catalysis 71 (1991) 363.Google Scholar
[14] Cimino, A., La Chimica el Industria 56 (1974) 27.Google Scholar
[15] Sundararajan, R. and Srinvasan, V., Applied Catalysis 73 (1991) 165.Google Scholar
[16] Eley, D.D., Klepping, A. H. and Moore, P.B., J. Chem. Soc, Faraday Trans. 1, 81 (1985) 2981.Google Scholar
[17] Akbar, S. and Joyner, R.W., J. Chem. Soc, Faraday Trans. 1, 77 (1981) 803.Google Scholar
[18] Oku, M. and Sato, Y., Applied Surface Sci. 55 (1992) 37.Google Scholar
[19] Li, N., Tan, T.C. and Zeng, H.C., J. Electrochem. Soc. 140 (1993) 1068.Google Scholar
[20] Perry, E.M. and Cocke, D.L., Applied Surface Sci. 44 (1990) 321.Google Scholar
[21] Gate, R.J. and Schmidt, L.D., Surf. Sci. 111 (1981) 348.Google Scholar
[22] Roberts, M.W., Adv. Catal. 29 (1980) 55.Google Scholar
[23] Mitton, D.B. and Walton, J. and Thompson, G.E., Surf. Interf. Anal. 20 (1993) 36.Google Scholar
[24] Barr, T.L., J. Vac. Sci. Technol. A 9 (1991) 1793.Google Scholar
[25] Zeng, H.C., Lin, J., Teo, W.K. and Tan, K.L., to be published.Google Scholar