Hostname: page-component-cd9895bd7-fscjk Total loading time: 0 Render date: 2024-12-27T02:28:27.823Z Has data issue: false hasContentIssue false

Catalytic Combustion Technology Development for Gas Turbine Engine Applications

Published online by Cambridge University Press:  15 February 2011

Robert N. Carter
Affiliation:
Precision Combustion, Inc., 25 Science Park, MS 24, New Haven, CT 06511USA
Lance L. Smith
Affiliation:
Precision Combustion, Inc., 25 Science Park, MS 24, New Haven, CT 06511USA
Hasan Karim
Affiliation:
Precision Combustion, Inc., 25 Science Park, MS 24, New Haven, CT 06511USA
Marco Castaldi
Affiliation:
Precision Combustion, Inc., 25 Science Park, MS 24, New Haven, CT 06511USA
Shah Etemad
Affiliation:
Precision Combustion, Inc., 25 Science Park, MS 24, New Haven, CT 06511USA
George Muench
Affiliation:
Precision Combustion, Inc., 25 Science Park, MS 24, New Haven, CT 06511USA
R. Samuel Boorse
Affiliation:
Precision Combustion, Inc., 25 Science Park, MS 24, New Haven, CT 06511USA
Paul Menacherry
Affiliation:
Precision Combustion, Inc., 25 Science Park, MS 24, New Haven, CT 06511USA
William C. Pfefferle
Affiliation:
Precision Combustion, Inc., 25 Science Park, MS 24, New Haven, CT 06511USA
Get access

Abstract

Catalytic combustion is one means of meeting increasingly strict emissions requirements for ground-based gas turbine engines for power generation. In conventional homogeneous combustion, high flame temperatures and incomplete combustion lead to emissions of oxides of nitrogen (NOx) and carbon monoxide (CO), and in lean premixed systems unburned hydrocarbons (UHC). However, catalyst-assisted reaction upstream of a lean premixed homogeneous combustion zone can increase the fuel/air mixture reactivity sufficiently to provide low CO/UHC emissions. Additionally, catalytic combustion extends the lean limit of combustion, thereby minimizing NOx formation by lowering the adiabatic flame temperature. An overview of this technology is presented including discussion of the many materials science and catalyst challenges that catalytic combustion poses ranging from the need for high temperature materials to catalyst performance and endurance. Results of ongoing development efforts at Precision Combustion, Inc. (PCI) are presented including modeling studies and experimental results from both bench-scale and combustor-scale studies.

Type
Research Article
Copyright
Copyright © Materials Research Society 1999

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

[1] For a more detailed description of gas turbine combustion see for example: Lefebvre, A.H., Gas Turbine Combustion, (Taylor and Francis, Bristol, PA) 1983.Google Scholar
[2] Heck, R.M. and Farrauto, R.J., Catalytic Air Pollution Control, Commercial Technology, (Van Nostrand Reinhold, New York, 1995) Chapters 10 & 11.Google Scholar
[3] Kolaczkowski, S.T., Trans. IChemE, 73, 168 (1995).Google Scholar
[4] Lee, J.H., Trimm, D.L., Fuel Proc. Technol., 42, 339 (1995).Google Scholar
[5] Betta, R.A. Dalla, Catal. Today, 35, 129 (1997).Google Scholar
[6] Carter, R.N., Roychoudhury, S., Muench, G., Karim, H., Pfefferle, W.C., Mat. Res. Soc. Symp. Proc., 454, 273 (1997).Google Scholar
[7] Roychoudhury, S., Muench, G., Bianchi, J.F., Pfefferle, W.C., and Gonzales, F., SAE Paper 971023, SAE International, Warrendale, PA, 1997.Google Scholar
[8] Kraemer, G., Strickland, T.R., Pfefferele, W.C., and Ritter, J., Proceedings of the International Joint Power Generation Conference, EC-Vol. 5, Book No. GO1072, 1997.Google Scholar