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Carrier Transport Dependence on Phosphorescent Materials in Polymer Based OLEDs

Published online by Cambridge University Press:  14 February 2012

Genichi Motomura
Affiliation:
NHK Science & Technology Research Laboratories, 1-10-11 Kinuta, Setagaya-ku, Tokyo 157–8510, Japan
Mitsunori Suzuki
Affiliation:
NHK Science & Technology Research Laboratories, 1-10-11 Kinuta, Setagaya-ku, Tokyo 157–8510, Japan
Takahisa Shimizu
Affiliation:
NHK Science & Technology Research Laboratories, 1-10-11 Kinuta, Setagaya-ku, Tokyo 157–8510, Japan
Hideo Fujikake
Affiliation:
NHK Science & Technology Research Laboratories, 1-10-11 Kinuta, Setagaya-ku, Tokyo 157–8510, Japan
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Abstract

The carrier transport properties in the emissive layer of phosphorescent polymer organic light-emitting diodes (OLEDs) were observed by time-of-flight (TOF) mobility measurements. The hole and electron mobilities in carrier transport polymer without iridium complexes were measured with high levels, 3 × 10-4 cm2/Vs (hole) and 1 × 10-3 cm2/Vs (electron), of non-dispersive transport. The hole and/or electron transport properties were degraded when the iridium complexes were included in the phosphorescent polymers. The complexes acted as a trap in the phosphorescent polymers when the energy levels of the iridium complexes were lower than that of the carrier transport polymer.

Type
Research Article
Copyright
Copyright © Materials Research Society 2012

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References

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