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Building 3D materials from adjustable 2D-units; towards the Design of new Bi-based compounds

Published online by Cambridge University Press:  26 January 2011

M. Colmont ,
D. Endara ,
M. Huvé ,
S.V. Krivovichev  and
O. Mentré
M. Colmont
Affiliation:
Unité de Catalyse et de Chimie du Solide, UMR 8181, bât C7, 59652 Villeneuve d’Ascq cedex, France,
D. Endara
Affiliation:
Unité de Catalyse et de Chimie du Solide, UMR 8181, bât C7, 59652 Villeneuve d’Ascq cedex, France,
M. Huvé
Affiliation:
Unité de Catalyse et de Chimie du Solide, UMR 8181, bât C7, 59652 Villeneuve d’Ascq cedex, France,
S.V. Krivovichev
Affiliation:
Department of Crystallography, St. Petersburg State University, University Emb. 7/9, St. Petersburg 199034, Russia
O. Mentré
Affiliation:
Unité de Catalyse et de Chimie du Solide, UMR 8181, bât C7, 59652 Villeneuve d’Ascq cedex, France,
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Abstract

In the Bi2O3-MO-P2O5 diagram, on the basis of previous compounds based on 2D-ribbon like units, we have predicted and prepared the infinite term. It contains [Bi2O2]2+ planes arranged within a never-observed crystallographic form. In this series, the ribbons-like units are polycations built on the linkage of n O(Bi,M)4 tetrahedra along their width and infinite in a perpendicular dimension. Hence, this novel form completes the continuous series of analogue compounds, whose building units now extend from the single chain to the infinite plane, via a number of discrete n values (2,3,4,5,6,7,8,9,10,11). The presented materials of formulae Bi4MP2O12 (M= Zn and Mg) roughly show the same crystal structure. However different arrangements of the groups located between the [Bi2O2]2+ planes are at the origin of a complex superstructure in the case of the zinc compounds.

Keywords

structuraloxideBi
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1309: Symposium EE – Solid-State Chemistry of Inorganic Materials VIII , 2011 , mrsf10-1309-ee01-10
Copyright
Copyright © Materials Research Society 2011

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References

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