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The Bonding of Fluorinated and Hydrogenated Ethers to Metal Surfaces: A Surface Science Approach to Tribology

Published online by Cambridge University Press:  28 February 2011

M.M. Walczak ,
P.K. Leavitt  and
P.A. Thiel
M.M. Walczak
Affiliation:
Department of Chemistry and Ames Laboratory, Iowa State University, Ames, Iowa 50011, USA
P.K. Leavitt
Affiliation:
Department of Chemistry and Ames Laboratory, Iowa State University, Ames, Iowa 50011, USA
P.A. Thiel
Affiliation:
National Science Foundation Presidential Young Investigator (1985-1989) and Camille and Henry Dreyfus Foundation Teacher-Scholar (1986-1990)
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Abstract

We report a surface science study of fluorinated and hydrogenated ethers adsorbed at a metal surface. Fluorinated ethers bond less strongly to ruthenium surfaces than the hydrogenated analogs, both for atomically-smooth and atomically-rough surfaces. For the hydrogenated ethers, 0.03 to 0.17 monolayers undergo decomposition, while fluorinated ethers do not decompose significantly.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 140: Symposium S – New Materials Approaches to Tribology: Theory and Applications , 1988 , 417
Copyright
Copyright © Materials Research Society 1989

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