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Blue Second-Harmonic Light Generation From A New Organic Single Crystal, 8-(4′-Acetylphenyl)-1,4-Dioxa-8-Azaspiro[4.5]Decane(Apda)

Published online by Cambridge University Press:  16 February 2011

Masakazu Sagawa ,
Hiroyuki Kagawa ,
Atsushi Kakuta  and
Makoto Kaji
Masakazu Sagawa
Affiliation:
Hitachi Research Laboratory, Hitachi, Ltd., 7–1–1, OMika-cho, Hitachi Ibaraki 319–12, Japan
Hiroyuki Kagawa
Affiliation:
Hitachi Research Laboratory, Hitachi, Ltd., 7–1–1, OMika-cho, Hitachi Ibaraki 319–12, Japan
Atsushi Kakuta
Affiliation:
Hitachi Research Laboratory, Hitachi, Ltd., 7–1–1, OMika-cho, Hitachi Ibaraki 319–12, Japan
Makoto Kaji
Affiliation:
Ibaraki Research Laboratory, Hitachi Chemical Co., Ltd., 4–13–1, Higashi-cho Hitachi, Ibaraki 317, Japan
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Abstract

A new second-order nonlinear optical organic Material, 8-(4′-acetylphenyl)-l,4-dioxa-8-azaspiro[4.5]decane (APDA) was synthesized as a frequency doubler emitting blue light. Its crystal growth, linear and non-linear optical properties were evaluated. The APDA crystal has a short cutoff wavelength of 384 nm and high nonlinear optical coefficients d33=50 pm/V and d32=7 pm/V. The crystal is phase matchable below wavelengths of 800nm, and its maximum effective nonlinear coefficient is 14.9 pm/V. Type I phase-Matched second harmonic generations can be carried out with YAG and Ti-sapphire laser pumping.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 328: Symposium Q – Electrical, Optical, and Magnetic Properties of Organic Solid State Materials , 1993 , 601
Copyright
Copyright © Materials Research Society 1994

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References

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