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Biomimetic Synthesis of Water Soluble Conductive Polypyrrole and Poly (3,4 ethylenedioxythiophene).

Published online by Cambridge University Press:  11 February 2011

Ferdinando F. Bruno ,
Jacqueline M. Fortier ,
Ramaswamy Nagarajan ,
Sucharita Roy ,
Jayant Kumar  and
Lynne A. Samuelson
Ferdinando F. Bruno
Affiliation:
Materials Science Team, Natick Soldier Center, U.S. Army Soldier and Biological, Chemical Command, Natick, MA 01760.
Jacqueline M. Fortier
Affiliation:
Departments of Physics and Chemistry, Center for Advanced Materials, University of Massachusetts Lowell, Lowell, MA 01854.
Ramaswamy Nagarajan
Affiliation:
Departments of Physics and Chemistry, Center for Advanced Materials, University of Massachusetts Lowell, Lowell, MA 01854.
Sucharita Roy
Affiliation:
Departments of Physics and Chemistry, Center for Advanced Materials, University of Massachusetts Lowell, Lowell, MA 01854.
Jayant Kumar
Affiliation:
Departments of Physics and Chemistry, Center for Advanced Materials, University of Massachusetts Lowell, Lowell, MA 01854.
Lynne A. Samuelson
Affiliation:
Materials Science Team, Natick Soldier Center, U.S. Army Soldier and Biological, Chemical Command, Natick, MA 01760.
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Abstract

A novel biomimetic method for the synthesis of a conducting molecular complex of polypyrrole and of Poly(3,4 ethylenedioxythiophene) (PEDOT) in the presence of a polyelectrolyte, such as polystyrene sulfonate (SPS) is presented. A poly(ethylene glycol) modified hematin (PEG-Hematin) was used to catalyze the polymerization of pyrrole and of 3,4 ethylenedioxythiophene in the presence of SPS to form a Polypyrrole/SPS and PEDOT/SPS complex. UV-vis, FTIR, electrical conductivity and TGA studies for all complexes indicate the presence of a thermally stable and electrically conductive form of these polymers. Furthermore the presence of SPS in this complex provides a unique combination of properties such as processability and water-solubility. Water-soluble polypyrrole opens new avenues for the fabrication of novel biosensors.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 736: Symposium D – Electronics on Unconventional Substrates–Electrotextiles and Giant-Area Flexible Circuits , 2002 , D7.13
Copyright
Copyright © Materials Research Society 2003

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References

REFERENCES

1) Dordick, J. S.; Marletta, M. A.; Klibanov, A. M.; Proc. Natl. Acad. Sci., USA 1986, 83, 6255.Google Scholar
2) Akkara, J. A.; Senecal, K. J.; Kaplan, D. L.; J. Poly. Sci.: Poly. Chem. 1991, 29, 1561.Google Scholar
3) Ikeda, R.; Uyama, H.; Kobayashi, S.; Macromolecules 1996, 29, 3053–3054.Google Scholar
4) Ryu, K.; McEldoon, J. P.; Pokora, A. R.; Cyrus, W.; Dordick, J. S.; Biotec. Bioeng. 1993, 42, 807.Google Scholar
5) Bruno, F. F., Akkara, J. A., Kaplan, D. L., Tripathy, S. K.; Ind. Eng. Chem. Res. 1995, 34, 4009 Google Scholar
6) Skotheim, T. A.; Elsenbaumer, R. L.; Reynolds, J. R.; (eds.), Handbook of Conducting Polymers, Marcel Dekker, New York 1998 Google Scholar
7) Pshezhetskii, V. S.; Jaroslavov, A. A. Febs Lett. 1974, 49, 29.Google Scholar
8) Gatt, R.; Kremer, M. L. Trans. Far. Soc. 1968, 64, 721.Google Scholar
9) Brown, S. B.; Jones, P. Trans. Far. Soc. 1968, 64, 999.Google Scholar
10) (a) Akkara, J. A.; Wang, J.; Yang, D-P.; Gonsalves, K. E. Macromolecules 2000, 33, 2377.Google Scholar
(b) Akkara, J. A. US Patent 6, 150, 491, Nov 21, 2000.Google Scholar
11) Bruno, F. F.; Nagarajan, R.; Roy, S.; Kumar, J.; Tripathy, S. K.; Samuelson, L. MRS Proceedings 2001, 660, JJ 8.6.1.Google Scholar
12) Liu, W.; Kumar, J.; Tripathy, S.; Senecal, K. J.; Samuelson, L. J. Am. Chem. Soc. 1999, 121, 71.Google Scholar
(c) Liu, W.; Cholli, A. L.; Nagarajan, R.; Kumar, J.; Tripathy, S.; Bruno, F. F.; Samuelson, L. A. J. Am. Chem. Soc 1999, 121, 11345.Google Scholar
13) Nagarajan, R; Liu, W; Kumar, J; Tripathy, S K.; Bruno, F. F.; Samuelson, L.A. Macromolecules 2001, 34, 3921.Google Scholar
14) (a) Roy, S.; Nagarajan, R.; Bruno, F. F.; Tripathy, S. K.; Kumar, J.; Samuelson, L. Proc. of the ACS, Division of PMSE 2001, 85, 202.Google Scholar
(b) Roy, S.; Fortier, J. M.; Nagarajan, R.; Tripathy, S. K.; Kumar, J.; Samuelson, L.; Bruno, F. F.; Biomacromolecules, 2002, 3(5), 937–941.Google Scholar
15) Ahonem, H. J.; Lukkari, J.; Hellström, , Mattila, J.: Kankare, J.; Synthetic Metals 2001, 119, 119. (and ref. in paper).Google Scholar