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Auger Recombination of Biexcitons and Charged Excitons in CdSe/CdS core/shell Nanocrystals

Published online by Cambridge University Press:  27 February 2012

Marco Marceddu ,
Michele Saba ,
Francesco Quochi ,
Adriano Lai ,
Jing Huang ,
Dmitri V. Talapin ,
Andrea Mura  and
Giovanni Bongiovanni
Marco Marceddu
Affiliation:
Centro Grandi Strumenti d’Ateneo, Università di Cagliari, I-09042 Monserrato (CA), Italy
Michele Saba
Affiliation:
Dipartimento di Fisica, Università di Cagliari, I-09042 Monserrato (CA), Italy
Francesco Quochi
Affiliation:
Dipartimento di Fisica, Università di Cagliari, I-09042 Monserrato (CA), Italy
Adriano Lai
Affiliation:
Istituto Nazionale di Fisica Nucleare, Sezione di Cagliari, I-09042 Monserrato, Italy
Jing Huang
Affiliation:
Department of Chemistry, The University of Chicago, Chicago, IL 60637, USA
Dmitri V. Talapin
Affiliation:
Department of Chemistry, The University of Chicago, Chicago, IL 60637, USA
Andrea Mura
Affiliation:
Dipartimento di Fisica, Università di Cagliari, I-09042 Monserrato (CA), Italy Istituto Officina dei Materiali del Consiglio Nazionale delle Ricerche (CNR-IOM) Unità SLACS, I-09042 Monserrato (CA), Italy
Giovanni Bongiovanni
Affiliation:
Dipartimento di Fisica, Università di Cagliari, I-09042 Monserrato (CA), Italy Istituto Officina dei Materiali del Consiglio Nazionale delle Ricerche (CNR-IOM) Unità SLACS, I-09042 Monserrato (CA), Italy
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Abstract

CdSe/CdS colloidal nanocrystals are light-emitting nanoparticles with remarkable optical properties such as suppressed fluorescence blinking and enhanced emission from multiexciton states. These properties have been attributed to the suppression of non-radiative Auger recombination. In this work we employ ultrafast spectroscopy techniques to identify optical signatures of neutral and charged excitonic and multiexcitonic states.

Keywords

optical propertiescore/shellluminescence
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1409: Symposium CC – Functional Semiconductor Nanocrystals and Metal-Hybrid Structures , 2012 , mrsf11-1409-cc11-04
Copyright
Copyright © Materials Research Society 2012

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References

REFERENCES

[1] 2003, Semiconductor and Metal Nanocrystals: Synthesis and Electronic and Optical Properties, edited by Klimov, V. I., Marcel Dekker, New York Google Scholar
[2] Klimov, V I, Mikhailovsky, A A, McBranch, D W, Leatherdale, C A, Bawendi, M G. 2000 Science 287, 1011.Google Scholar
[3] Mahler, B, Spinicelli, P, Buil, S, Quelin, X, Hermier, J-P, Dubertret, B. 2008 Nature Mat. 7, 659 Google Scholar
[4] Yongfen Chen, Y, Vela, J, Htoon, H, Casson, J L, Werder, D J, Bussian, D A, Klimov, V I, Hollingsworth, J A. 2008 J. Am. Chem. Soc. 130, 5026 Google Scholar
[5] Wang, X, Ren, X, Kahen, K, Hahn, M A, Rajeswaran, M, Maccagnano-Zacher, S, Silcox, J, Cragg, J E, Efros, A L, Krauss, T D. 2009 Nature 459, 686 Google Scholar
[6] Osovsky, R, Cheskis, D, Kloper, V, Sashchiuk, A, Kroner, M, Lifshitz, E. 2009 Phys. Rev. Lett. 102, 197401 Google Scholar
[7] Cragg, G.E, Efros, A L. 2010 Nano Lett. 10, 313 Google Scholar
[8] Garcia-Santamaria, F, Brovelli, S, Viswanantha, R, Hollingsworth, J A, Htoon, H, Crooker, S A, Klimov, V I. 2011 Nano Lett. 11(2), pp 687–693 Google Scholar
[9] Garcia-Santamaria, F, Chen, Y F, Vela, J, Schaller, R D, Hollingsworth, J A, Klimov, V I. 2009 Nano Lett. 9, 3482 Google Scholar
[10] Htoon, H, Malko, A V, Bussian, D, Vela, J, Chen, Y, Hollingsworth, J A, Klimov, V I. 2010 Nano Lett. 10, 2401 Google Scholar
[11] Zavelani-Rossi, M, Lupo, M G, Tassone, F, Manna, L, Lanzani, G. 2010 Nano Lett. 10, 3142 Google Scholar
[12] Lutich, A A, Mauser, Ch, Da Como, E, Huang, J, Vaneski, A, Talapin, D V, Rogach, A L, Feldmann, J. 2010 Nano Lett., DOI: 10.1021/nl1028057 Google Scholar
[13] Cretí, A, Anni, M, Zavelani Rossi, M, Lanzani, G, Leo, G, Della Sala, F, Manna, L, Lomascolo, M. 2005 Phys. Rev. B 72, 125346 Google Scholar
[14] Lupo, M G, Della Sala, F, Carbone, L, Zavelani-Rossi, M, Fiore, A, Luer, L, Polli, D, Cingolani, R, Manna, L, Lanzani, G. 2008 Nano Lett. 8, 4582 Google Scholar
[15] Saba, M, Minniberger, S, Quochi, F, Roither, J, Marceddu, M, Kovalenko, M V, Talapin, D V, Heiss, W, Mura, A, Bongiovanni, G. 2009 Adv. Mat. 21, 4942 Google Scholar
[16] Mauser, Ch, Da Como, E, Baldauf, J, Huang, J, Vaneski, A, Talapin, D V, Rogach, A L, Feldmann, J. 2010 Phys. Rev. B 82, 081306 Google Scholar
[17] Kambhampati, P., 2011 Accounts of Chemical Research, 44, 1–13 Google Scholar
[18] Sewall, S L, Cooney, R R, Anderson, K E H, Dias, E A, Sagar, D M, Kambhampati, P. 2008 The Journal of Chemical Physics 129, 084701 Google Scholar
[19] Cooney, R R, Sewall, S L, Sagar, D M, Kambhampati, P. 2009 The Journal of Chemical Physics 131, 164706 Google Scholar
[20] Sewall, S L, Cooney, R R, Anderson, K E H, Dias, E A, and Kambhampati, P. 2006 Physical Review B 74, 235328 Google Scholar
[21] Tyagi, P, Cooney, R R, Sewall, S L, Sagar, D M, Saari, J I, and Kambhampati, P. 2010 Nano Lett. 10, 3062–3067 Google Scholar
[22] Tyagi, P and Kambhampati, P. 2011 The Journal of Chemical Physics 134, 094706 Google Scholar
[23] Wang, C, Wehrenberg, B.L.; Woo, C.Y.; Guyot-Sionnest, P.; 2004 J. Phys. Chem. B 108, 9027 Google Scholar
[24] Jha, P P, Guyot-Sionnest, P. 2009 ACS Nano 3, 1011.Google Scholar
[25] Spinicelli, P, Buil, S, Quélin, X, Mahler, B, Dubertret, B, Hermier, J.-P. 2009 Phys. Rev. Lett. 102, 136801 Google Scholar
[26] Gómez, D E, van Embden, J, Mulvaney, P, Fernée, M J, Rubinsztein-Dunlop, H. 2009 ACS Nano 3, 2281 Google Scholar
[27] Zhao, J, Nair, G, Fisher, B R, Bawendi, MG. 2010 Phys. Rev. Lett. 104, 157403 Google Scholar
[28] Louyer, Y, Biadala, L, Tamarat, Ph, Lounis, B. 2010 Appl. Phys. Lett. 96, 203111 Google Scholar
[29] Talapin, D V, Koeppe, R, Goetzinger, S, Kornowski, A, Lupton, J M, Rogach, A L, Benson, O, Feldmann, J. 2003 Nano Lett. 3, 1677 Google Scholar
[30] Talapin, D V, Nelson, J H, Shevchenko, E V, Aloni, S, Sadtler, B, Alivisatos, A P. 2007 Nano Lett. 7, 2951 Google Scholar
[31] Carbone, L, Nobile, C, De Giorgi, M, Sala, F D, Morello, G, Pompa, P, Hytch, M, Snoeck, E, Fiore, A, Franchini, I R, Nadasan, M, Silvestre, A F, Chiodo, L, Kudera, S, Cingolani, R, Krahne, R, Manna, L. 2007 Nano Lett. 7, 2942 Google Scholar
[32] Dabbousi, B O, Rodriguez-Viejo, J, Mikulec, F V, Heine, J R, Mattoussi, H, Ober, R, Jensen, K F, Bawendi, M G. 1997 J. Phys. Chem. B 101, 9463. Peng, X, Schlamp, M. C, Kadavanich, A, Alivisatos, A. P. 1997 J. Am. Chem. Soc. 119, 7019 Google Scholar
[33] Norris, D J, Bawendi, M G. 2006 Phys. Rev. B 53, 16338 Google Scholar
[34] Nair, G, Zhao, J, Bawendi, M G. 2011 Nano Lett. 11, 1136 Google Scholar