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Atomistic modeling of Ru nanocluster formation on graphene/Ru(0001): Thermodynamically versus kinetically directed-assembly

Published online by Cambridge University Press:  07 February 2013

Y. Han ,
A. K. Engstfeld ,
C.-Z. Wang ,
L. D. Roelofs ,
R. J. Behm  and
J. W. Evans
Y. Han
Affiliation:
Department of Physics and Astronomy, Iowa State University, Ames, Iowa 50011, USA
A. K. Engstfeld
Affiliation:
Institute of Surface Chemistry and Catalysis, Ulm University, D-89069, Ulm, Germany
C.-Z. Wang
Affiliation:
Ames Laboratory—USDOE, Iowa State University, Ames, Iowa 50011, USA
L. D. Roelofs
Affiliation:
Colgate University, Hamilton, New York, 13346, USA
R. J. Behm
Affiliation:
Institute of Surface Chemistry and Catalysis, Ulm University, D-89069, Ulm, Germany
J. W. Evans
Affiliation:
Department of Physics and Astronomy, Iowa State University, Ames, Iowa 50011, USA Ames Laboratory—USDOE, Iowa State University, Ames, Iowa 50011, USA
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Abstract

Atomistic lattice-gas models for thermodynamically and kinetically directed assembly are applied to Ru nanocluster formation on a monolayer of graphene supported on Ru(0001) at 309 K. Nanocluster density, mean size, height distribution, and spatial ordering are analyzed by kinetic Monte Carlo simulations. Both models can reproduce the experimental data, but additional density functional theory analysis favors the former.

Keywords

cluster assemblynucleation & growthscanning tunneling microscopy (STM)
Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1498: Symposium S – Biomimetic, Bio-inspired and Self-Assembled Materials for Engineered Surfaces and Applications , 2013 , pp. 249 - 254
Copyright
Copyright © Materials Research Society 2013 

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References

REFERENCES

Marchini, S., Günther, S., and Wintterlin, J., Phys. Rev. B 76, 075429 (2007).CrossRefGoogle Scholar
Pan, Y., Shi, D.-X, and Gao, H.-J., Chin. Phys. 16, 3151 (2007).Google Scholar
Vázquez de Parga, A. L., Calleja, F., Borca, B., Passeggi, M. C. G., Hinarejos, J. J., Guinea, F., and Miranda, R., Phys. Rev. Lett. 100, 056807 (2008).CrossRefGoogle Scholar
Borca, B., Barja, S., Garnica, M., Minniti, M., Politano, A., Rodriguez-García, J. M., Hinarejos, J. J., Farías, D., Vázquez de Parga, A. L., and Miranda, R, New J. Phys. 12, 093018 (2010).CrossRefGoogle Scholar
Moritz, W., Wang, B., Bocquet, M.-L., Brugger, T., Greber, T., Wintterlin, J., and Günther, S., Phys. Rev. Lett. 104, 136102 (2010).CrossRefGoogle Scholar
Wang, B., Günther, S., Wintterlin, J., and Bocquet, M.-L., New J. Phys. 12, 043041 (2010).CrossRefGoogle Scholar
Pan, Y., Gao, M., Huang, L., Liu, F., and Gao, H.-J., Appl. Phys. Lett. 95, 093106 (2009).CrossRefGoogle Scholar
Donner, K. and Jakob, P., J. Chem. Phys. 131, 164701 (2009).CrossRefGoogle Scholar
Zhao, Z., Gao, F., and Goodman, D.W., Surf. Sci. 604, L31 (2010).CrossRefGoogle Scholar
Sutter, E., Albrecht, P., Wang, B., Bocquet, M.-L., Wu, L., Zhu, Y., and Sutter, P., Surf. Sci. 605, 1676 (2011).CrossRefGoogle Scholar
Engstfeld, A. K., Hoster, H. E., Behm, R. J., Roelofs, L. D., Liu, X., Wang, C.-Z., Han, Y., and Evans, J. W., Phys. Rev. B 86, 085442 (2012).CrossRefGoogle Scholar
Evans, J. W., Thiel, P. A., and Bartelt, M. C., Surf. Sci. Rep. 61, 1 (2006).CrossRefGoogle Scholar
Wang, B., Bocquet, M.-L., J. Phys. Chem. Lett. 2, 2341 (2011).CrossRefGoogle Scholar