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Atmospheric Pressure Plasma Functionalization of Dry-spun Multi-walled Carbon Nanotubes Sheets and its application in CNT-Polyvinyl Alcohol (PVA) Composites

Published online by Cambridge University Press:  31 May 2013

Rachit Malik ,
Yi Song ,
Noe Alvarez ,
Brad Ruff ,
Mark Haase ,
Bolaji Suberu ,
Andrew Gilpin ,
Mark Schulz  and
Vesselin Shanov
Rachit Malik
Affiliation:
School of Energy, Environment, Biological and Medical Engineering, University of Cincinnati, Cincinnati, OH 45221, USA.
Yi Song
Affiliation:
School of Dynamic Systems, Nanoworld Laboratories, University of Cincinnati, Cincinnati, OH 45221, USA.
Noe Alvarez
Affiliation:
School of Energy, Environment, Biological and Medical Engineering, University of Cincinnati, Cincinnati, OH 45221, USA.
Brad Ruff
Affiliation:
School of Dynamic Systems, Nanoworld Laboratories, University of Cincinnati, Cincinnati, OH 45221, USA.
Mark Haase
Affiliation:
School of Energy, Environment, Biological and Medical Engineering, University of Cincinnati, Cincinnati, OH 45221, USA.
Bolaji Suberu
Affiliation:
School of Dynamic Systems, Nanoworld Laboratories, University of Cincinnati, Cincinnati, OH 45221, USA.
Andrew Gilpin
Affiliation:
School of Energy, Environment, Biological and Medical Engineering, University of Cincinnati, Cincinnati, OH 45221, USA.
Mark Schulz
Affiliation:
School of Dynamic Systems, Nanoworld Laboratories, University of Cincinnati, Cincinnati, OH 45221, USA.
Vesselin Shanov
Affiliation:
School of Energy, Environment, Biological and Medical Engineering, University of Cincinnati, Cincinnati, OH 45221, USA.
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Abstract

Robust sheets comprised of aligned multi-walled carbon nanotubes (MWNTs) drawn from spin-able carbon nanotube (CNT) arrays were developed. Surface modification of these sheets was carried out via an atmospheric pressure plasma jet as a post-treatment process. Helium/Oxygen plasma was utilized to produce carboxyl (-COO-) functionality on the surface of the nanotubes. Raman Spectroscopy, X-Ray Photoelectron Spectroscopy (XPS) and Fourier Transform Infrared (FTIR) Spectroscopy confirm the presence of functional groups on the nanotube surface. Composite laminates made from functionalized CNT sheets in a polyvinyl alcohol (PVA) matrix demonstrate increase in tensile strength over those made with pristine sheets used as reinforcement material.

Keywords

compositepolymerchemical vapor deposition (CVD) (deposition)
Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1574: Symposium UU – Plasma and Low-Energy Ion-Beam-Assisted Processing and Synthesis of Energy-Related Materials , 2013 , mrss13-1574-uu03-04
Copyright
Copyright © Materials Research Society 2013 

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References

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