Hostname: page-component-cd9895bd7-gvvz8 Total loading time: 0 Render date: 2024-12-24T17:50:10.821Z Has data issue: false hasContentIssue false
  • English
  • Français

Assembly of Tailored Thiophene Oligomers on Gold Electrodes - Film Formation and Properties

Published online by Cambridge University Press:  26 February 2011

Peter Anthony Collier ,
Theivanayagam Chairman Deivaraj ,
Wai Tat Kerk ,
Wee Shong Chin ,
Kian Ping Loh ,
Ping Bai  and
Er Ping Li
Peter Anthony Collier
Affiliation:
[email protected], Singapore Institute of Manufacturing Technology, Surface Technology Group, 71 Nanyang Drive, Singapore, 638075, Singapore, (65) 6793 8531, (65) 6791 6377
Theivanayagam Chairman Deivaraj
Affiliation:
[email protected], Singapore Institute of Manufacturing Technology, Surface Technology Group, 71 Nanyang Drive, Singapore, 638075, Singapore
Wai Tat Kerk
Affiliation:
[email protected], Singapore Institute of Manufacturing Technology, Surface Technology Group, 71 Nanyang Drive, Singapore, 638075, Singapore
Wee Shong Chin
Affiliation:
[email protected], National University of Singapore, Department of Chemistry, 3 Science Drive 3, Singapore, 117543, Singapore
Kian Ping Loh
Affiliation:
[email protected], National University of Singapore, Department of Chemistry, 3 Science Drive 3, Singapore, 117543, Singapore
Ping Bai
Affiliation:
[email protected], Institute of High Performance Computing, Electronics and Electromagnetics Program, 1 Science Park Road, #01-01 The Capricorn, Science Park II, Singapore, 117528, Singapore
Er Ping Li
Affiliation:
[email protected], Institute of High Performance Computing, Electronics and Electromagnetics Program, 1 Science Park Road, #01-01 The Capricorn, Science Park II, Singapore, 117528, Singapore
Get access

Abstract

To examine the potential to apply chemically modified surfaces in organic thin film transistors (TFT), we report the synthesis and characterization of two tailored series of oligothiophene compounds. The oligomers have thiol end groups for coupling to gold electrodes and have regio-regular alkyl substitutions corresponding to Head-Head (HH-) and Head-Tail (HT-) molecular conformations. Variations in chain length, structures and end groups have enabled a detailed study of the deposition of films from solution and the films' properties.

Keywords

self-assemblyorganicelectrical properties
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 965: Symposium S – Organic Electronics – Materials, Devices and Applications , 2006 , 0965-S14-09
Copyright
Copyright © Materials Research Society 2007

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Ulman, A., An Introduction to Ultrathin Organic Films, (Academic Press: Boston, MA, 1991).Google Scholar
2. Garnier, F., Yassar, A., Hajlaoui, R., Horowitz, G., Delottre, F., Servet, B., Reis, S. and Alnot, P., J. Am. Chem. Soc., vol. 115, 8716 (1993).Google Scholar
3. Tour, J.M., Jones, L. II, Pearson, D.L., Lamba, J.J.S., Burgin, T.P., Whitesides, G.M., Allara, D.L., Parikh, A.N. and Atre, S., J. Am. Chem. Soc., 117, 9529 (1995).Google Scholar
4. Ng, S.C., Miao, P., Chen, Z. and Chan, H.S.O., Adv. Mater. 10, 782 (1998).Google Scholar
5. Dishner, M.H., Hemminger, J.C., and Feher, F.J., Langmuir, 12, 6176 (1996).Google Scholar
6. McCullough, R.D., Ewbank, P.C., and Loewe, R.S., J. Am. Chem. Soc. 119, 633 (1997).Google Scholar
7. Peng, Z., and Dong, S., Langmuir, 17, 4904 (2001).Google Scholar
8. Deivaraj, T.C., Collier, P.A., Kerk, W. T., Chin, W. S., Loh, K. P., Bai, P., Li, E.P., Sixth IEEE Conference on Nanotechnology, Volume 2, 666–670 (2006).Google Scholar
9. Deivaraj, T.C., Collier, P.A., Kerk, W.T., Chin, W.S. and Loh, K.P., presented at International Society of Electrochemistry, ISE Spring Meeting 2006, Singapore, 17th – 20th April 2006.Google Scholar
10. Woods, R. in Electroanalytical Chemistry, Volume 9, Edited by Bard, A.J., (Marcel Dekker, New York, 1976).Google Scholar
11. Bai, P., Li, E.P., Ong, E. A., Collier, P.A., Loh, K.P., Chin, W.S., Sixth IEEE Conference on Nanotechnology, Volume 2, 492–495 (2006).Google Scholar