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The Application of 57FE Mössbauer Spectroscopy to the Characterization of Nuclear Waste Forms

Published online by Cambridge University Press:  15 February 2011

Paul G. Huray ,
M. T. Spaar ,
S. E. Nave ,
J. M. Legan ,
L. A. Boatner  and
M. M. Abraham
Paul G. Huray
Affiliation:
University of Tennessee Physics Department, Knoxville, Tennessee, 37916 and Chemistry Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee, 37830
M. T. Spaar
Affiliation:
University of Tennessee Physics Department, Knoxville, Tennessee, 37916 and Chemistry Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee, 37830
J. M. Legan
Affiliation:
University of Tennessee Physics Department, Knoxville, Tennessee, 37916 and Chemistry Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee, 37830
L. A. Boatner
Affiliation:
Solid State Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37830
M. M. Abraham
Affiliation:
Solid State Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37830
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Extract

The electronic charge states and site symmetries of the radioactive ions incorporated in nuclear waste forms are of considerable importance in determining the physical and chemical properties of these materials. An in situ characterization of these ions is, unfortunately, often difficult – especially when a mixture of charge states and local crystal symmetries exist. The application of Mbssbauer spectroscopy represents a powerful technique for obtaining solid state chemical information.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 6: Symposium D – Scientific Basis for Nuclear Waste Management IV , 1981 , 59
Copyright
Copyright © Materials Research Society 1982

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References

REFERENCES

1. Abraham, M. M., Boatner, L. A., Quinby, T. C., Thomas, D. K., and Rappaz, M., Radioactive Waste Management 1, 181 (1980).Google Scholar
2. Huray, P. G., Bamberger, C. E., Spaar, M T., and Nave, S. E. (to be published).Google Scholar
3. Mattievich, E. and Danon, J., J. Physique Colloq. 37, C6–483 (1976).Google Scholar