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Anomalous Surface Diffusion of Water in Nanopores

Published online by Cambridge University Press:  10 February 2011

J.-P. Korb  and
R. G. Bryant
J.-P. Korb
Affiliation:
Laboratoire de Physique de la Matière Condensée, CNRS, Ecole Polytechnique, 91128 Palaiseau, France
R. G. Bryant
Affiliation:
Department of Chemistry, University of Virginia, Charlottesville, VA 22901
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Abstract

Proton nuclear magnetic relaxation dispersion experiments show remarkable differences between water and aprotic liquids in contact with microporous glass surfaces containing trace paramagnetic impurities. Proton surface diffusion permits long range effectively 1-dimensional exploration along the pores for water. This gives a direct measurement of the translational diffusion coefficient at the pore surface.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 543: Symposium W – Dynamics in Small Confining Systems IV , 1998 , 97
Copyright
Copyright © Materials Research Society 1999

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References

[1] Kimmich, R., Weber, H. W., Phys.Rev. B 47, 11788 (1993)Google Scholar
[2] Whaley, M., Lawrence, A. J., Korb, J. -P., Bryant, R. G., Sol. Staic. Nucl.Magn. Reson 7, 247 (1996).Google Scholar
[3] Korb, J. -P., Whaley-Hodges, M., Bryant, R. G., Phys.Rev. E 50, 1934 (1997).Google Scholar
[4] Bellissent-Funel, M. C., Chen, S. H., and Zanotti, J. M., Phys. Rev. E 51, 4558 (1994).Google Scholar
[5] Sur, S. K. and Bryant, R. G., J. Phys Chem 99, 6301(1995).Google Scholar
[6] Redfield, A. G.. Fite, W.. and Bleich, H. E., Rev. Sci. Instrum. 39, 710 (1968).Google Scholar
[7] Koenig, S. H. and Schillinger, W. E., J. Biol. Chem. 12, 3283 (1969).Google Scholar
[8] Hernandez, G.. Tweedle, M. F.. Brittain, H., and Bryant, R. G., Inorg. Chem. 29, 985 (1990).Google Scholar
[9] Korringa, J., Seevers, D. O. and Torrey, H. C., Phys. Rev. 127, 1143 (1962).Google Scholar
[10] Korb, J. -P.. Malier, L., Cros, F., Xu, Shu, and Jonas, J., Phys. Rev. Lett. 77, 2312 (1996).Google Scholar
[11] Abragam, A., The Principles of Nuclear Magnetism (Clarendon Press, Oxford, 1961).Google Scholar
[12] Bloembergen, N. and Morgan, L. O.. J.Chem Phys. 34, 842 (1961).Google Scholar
[13] Korb, J. -P.. Gobron, T., Bryant, R. G.. Phys. Rev E (submitted)Google Scholar