Hostname: page-component-586b7cd67f-t7fkt Total loading time: 0 Render date: 2024-11-29T07:35:28.875Z Has data issue: false hasContentIssue false
  • English
  • Français

An Overview of Conjugated Polymers in their Insulating Forms

Published online by Cambridge University Press:  25 February 2011

Daniel J. Sandman
Daniel J. Sandman*
Affiliation:
GTE Laboratories Incorporated, 40 Sylvan Road, Waltham, MA 02254, U. S. A.
Get access

Abstract

A brief overview is presented of the electrical and linear optical properties of conjugated polymers in their electrically insulating forms. Topics discussed include electronic structure and optical spectroscopy, thermochromism, and device applications, particularly electroluminescence. Structure-property relationships are stressed. Particular emphasis is placed on the properties of polydiacetylenes as they are available as macroscopic single crystals and, hence, are the best defined class of conjugated polymers.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 247: Symposium N – Electrical, Optical, and Magnetic Properties of Organic Solid State Materials , 1992 , 631
Copyright
Copyright © Materials Research Society 1992

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

[1] Sandman, D. J., in 1991 McGraw-Hill Yearbook of Science and Technology, McGraw-Hill, Inc., New York, pp. 71–75 (1990).Google Scholar
[2] Bredas, J. L. and Chance, R. R., editors, Conjugated Polymeric Materials: Opportunities in Electronics, Optoelectronics, and Molecular Electronics, Kluwer Academic Publishers, Dordrecht, Boston (1990).Google Scholar
[3] Salaneck, W. R., Clark, D. T., Samuelsen, E. J., editors, Science and Applications of Conducting Polymers, Adam Hilger, Bristol, Philadelphia (1991).Google Scholar
[4] Hanack, M., Roth, S., Schier, H., editors, Proceedings of ICSM '90, Tübingen, F. R. G., September 2–7, 1990, Synthetic Metals, 41–43 (1991).Google Scholar
[5] Sandman, D. J., editor, Crystallographically Ordered Polymers, American Chemical Society Symposium Series, Vol. 337 (1987).Google Scholar
[6] Bloor, D. and Chance, R. R., editors, Polydiacetylenes, Martinus Nijhoff, Dordrecht, Boston (1985).Google Scholar
[7] Enkelmann, V., in Polydiacetylenes, edited by Cantow, H. H., Advances in Polymer Science, Springer Verlag, Berlin, Heidelberg, Vol. 63, pp. 91–136 (1984).Google Scholar
[8] Bässler, H., in ref. 6, pp. 135–153.Google Scholar
[9] Batchelder, D. N., in ref. 6, pp. 187–222.Google Scholar
[10] (a) Bässler, H., in Optical Techniques to Characterize Polymer Systems, edited by Bässler, H., Elsevier Science Publishers, Amsterdam, 1989, pp. 181–225;Google Scholar
(b) Mahrt, R., Yang, J., Greiner, A., Bässler, H., and Bradley, D.D.C., Makromol. Chem., Rapid Commun. 11, 415–421 (1990).Google Scholar
[11] Pellegrin, E., Fink, J., and Drechsler, S. L., Phys. Rev. Lett. 66, 2022–2025 (1991).Google Scholar
[12] Weiser, G., Phys. Rev. B, in press.Google Scholar
[13] Becker, R., Blöchl, G., Bräunung, H., in ref. 2, pp. 133–139.Google Scholar
[14] Hanack, M., Hieber, G., Dewald, G., and Ritter, H., in ref. 3, pp. 153–160.Google Scholar
[15] Wudl, F., Kobayashi, M., and Heeger, A. J., J. Org. Chem. 49, 3382–3384 (1984).Google Scholar
[16] Wright, J. D., Molecular Crystals, Cambridge University Press, Chapter 6, p. 96 (1987).Google Scholar
[17] Sandman, D. J., Mol. Cryst. Liq. Cryst. 189, 273–278 (1991).Google Scholar
[18] Gamier, F., Horowitz, G., Fichou, D., and Peng, X., in ref. 3, pp. 73–80.Google Scholar
[19] Schein, L. B., Phys. Rev. B. 15, 1024–1034 (1977).Google Scholar
[20] Gamier, F., Horowitz, G., Peng, X., and Fichou, D., Adv. Mater, 2, 592–594 (1990).Google Scholar
[21] Bloor, D., Nature (London), 349 738–739 (1991).Google Scholar
[22] Hartman, W. A. and Armstrong, H. L., J. Appl. Phys. 38, 2393–2395 (1967).Google Scholar
[23] Armstrong, H. L. and Hartman, W. A., Can. J. Phys. 42, 823–824 ( 1964).Google Scholar
[24] Partridge, R. H., Polymer 24, 748, 755 (1983).Google Scholar
[25] Burroughs, J. H., Bradley, D. D. C., Brown, A.R., Marks, R. N., Mackey, K., Friend, R. H., Burns, P. L., and Holmes, A. B., Nature (London) 347, 539–541 (1990).Google Scholar