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An Analysis of the Photo-Polymerization Induced Phase Separation Process in Liquid Crystal/Polymer Composite Films

Published online by Cambridge University Press:  10 February 2011

Toru Fujisawa
Affiliation:
Dainippon Ink & Chemicals, Inc. Central Laboratories 631, Sakado, Sakura-shi, Chiba-ken, Japan, 285-0078
Masanao Hayasi
Affiliation:
Dainippon Ink & Chemicals, Inc. Central Laboratories 631, Sakado, Sakura-shi, Chiba-ken, Japan, 285-0078
Hidetoshi Nakada
Affiliation:
Dainippon Ink & Chemicals, Inc. Central Laboratories 631, Sakado, Sakura-shi, Chiba-ken, Japan, 285-0078
Sigeru Matumoto
Affiliation:
Dainippon Ink & Chemicals, Inc. Central Laboratories 631, Sakado, Sakura-shi, Chiba-ken, Japan, 285-0078
Yuitiro Tani
Affiliation:
Dainippon Ink & Chemicals, Inc. Central Laboratories 631, Sakado, Sakura-shi, Chiba-ken, Japan, 285-0078
Makoto Yada
Affiliation:
Dainippon Ink & Chemicals, Inc. Central Laboratories 631, Sakado, Sakura-shi, Chiba-ken, Japan, 285-0078
Masao Aizawa
Affiliation:
Dainippon Ink & Chemicals, Inc. Central Laboratories 631, Sakado, Sakura-shi, Chiba-ken, Japan, 285-0078
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Abstract

We have analyzed the micro-phase separation during photo-polymerization in the liquid crystal/polymer composite films for a variety of light-control applications. The photo-polymerization induced phase separation process is remarkably affected by the reactivity in diacrylates and the fraction volume in liquid crystals. It is presumed that the nematic transition in a liquid crystal-rich phase and the reactivity play an important role to determine the morphology.

Type
Research Article
Copyright
Copyright © Materials Research Society 1999

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References

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