Hostname: page-component-cd9895bd7-hc48f Total loading time: 0 Render date: 2024-12-27T02:36:56.240Z Has data issue: false hasContentIssue false
  • English
  • Français

Alteration of Basaltic Glass in Iceland as a Natural Analogue for Nuclear Waste Glasses: Geochemical Modelling with DISSOL

Published online by Cambridge University Press:  26 February 2011

J. L. Crovisier ,
T. Advocat ,
J. C. Petit  and
B. Fritz
J. L. Crovisier
Affiliation:
C.S.G.S. (CNRS), 1, rue Blessig 67000 Strasbourg, FRANCE
T. Advocat
Affiliation:
C.S.G.S. (CNRS), 1, rue Blessig 67000 Strasbourg, FRANCE
J. C. Petit
Affiliation:
CEA, (SESD/LECALT), CEN-FAR, B.P.6, 92265 Fontenay-aux-roses, FRANCE
B. Fritz
Affiliation:
C.S.G.S. (CNRS), 1, rue Blessig 67000 Strasbourg, FRANCE
Get access

Abstract

The long term geochemical consequences of basaltic glass dissolution in fresh water at 0°C have been calculated with the computer code DISSOL. The clay minerals were represented by an ideal solid solution model (CISSFIT) able to describe variations in chemical composition of a clay phase in response to variations of the solution chemistry. The predicted mineral phases were iron hydroxides followed by kaolinite, TOT clays, chabazite and cli-noptilolite. These results are in reasonably good agreement with experimental results and observations of altered subglacial hyaloclastites from Iceland. The formation of secondary products are mainly controlled by thermodynamic constraints. Kinetic effects, such as diffusion in the near glass surface are not important.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 127: Symposium BERLIN – Scientific Basis for Nuclear Waste Management XII , 1988 , 57
Copyright
Copyright © Materials Research Society 1989

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Ewing, R.C. and Jercinovic, M.J. in Scientific Basis for Nuclear Waste Management, (Mater. Res. Symp. Proc. 84, Pittsburgh, Pa 1987) 67–83.Google Scholar
2. Lutze, W., Malow, G., Ewing, R.C., Jercinovic, M.J. and Keil, K., Nature, 314, 252–255 (1985).CrossRefGoogle Scholar
3. Crovisier, J.L., Fritz, B., Grambow, G. and Eberhart, J.P., in Scientific Basis for Nuclear Waste Management IX, edited by Werme, L.O. (Mater. Res. Soc. Proc. 50, Pittsburgh, PA 1985) pp. 274–280.Google Scholar
4. Fritz, B., Sci. Géol. Mém., Strasbourg 41 152p. (1975).Google Scholar
5. Fritz, B., Sci. Géol. Mém., Strasbourg 65, 197p. (1981).Google Scholar
6. Saemundsson, K., Acta Naturalia Islándica II, 7, 105p. (1967).Google Scholar
7. Saemundsson, K. and Noll, H., Jökull, 24, pp. 40–59 (1975).Google Scholar
8. Crovisier, J.L., Atassi, H., Daux, V., Honnorez, J., Petit, J.C. and Eberhart, J.P. in Scientific Basis for Nuclear Waste Management, (this volume').Google Scholar
9. Helgeson, H. C., Amer. J. Sci. 267 724–804 (1969).Google Scholar
10. Tardy, Y. and Fritz, B., Clay Minerals, 16, 361–373 (1981).Google Scholar
11. Honnorez, J., La palagonitisation: l'altération sous-marine du verre volca nique basique de Palagonia (Sicile). (Vulkaninstitut Immanuel Friedlaender, Birkhaüser Verlag, Basel, 9 (1972) 131p.Google Scholar
12. Grambow, B., pp. 15–27.Google Scholar
13. Grambow, B., Jercinovic, M.C., Ewing, R.C. and Byers, C.D., in Scientific Basis for Nuclear Waste Management IX, edited by Werme, L.O. (Mater. Res. Soc. Proc. 50, Pittsburgh, PA 1985) pp. 264–272.Google Scholar
14. Wagman, D.D., Evans, W.H., Parker, V.B., Halow, I., Bailey, S.M. and Schumm, R.H., US. Nat. Bur. Stand. Tech. Note 270 (1968) 264p.Google Scholar
15. Helgeson, H.C., Delany, J.M., Nesbitt, H.W. and Bird, D.K., Amer. J. Sci., 274, (1978) 1089–1198.Google Scholar
16. Kosiur, D.R., PhD thesis, University of California, Los Angeles 1978.Google Scholar